Main Title |
Structure and reactivity of adsorbed oxides of sulfur / |
Author |
Lunsford., Jack H.
|
CORP Author |
United States. Environmental Protection Agency. Office of Research and Development. |
Publisher |
United States Environmental Protection Agency Office of Research and Development, |
Year Published |
1974 |
Report Number |
EPA-650/3-74-006; EPA-801136; EPA-ROAP-21AJX |
Stock Number |
PB-245 046 |
OCLC Number |
21388441 |
Subjects |
Sulfur compounds ;
Sulphur compounds
|
Additional Subjects |
Sulfur oxide ;
Chemisorption ;
Adsorption ;
Surface chemistry ;
Magnesium oxides ;
Sulfur dioxide ;
Molecular structure ;
Free radicals ;
Ions ;
Infrared spectra ;
Sulfates ;
Sulfites ;
Electron paramagnetic resonance ;
Chemical bonds ;
Metal oxides ;
Chemical reactivity
|
Internet Access |
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
EJBD |
EPA 650-3-74-006 |
c.1 |
Headquarters Library/Washington,DC |
05/17/2013 |
ELBD ARCHIVE |
EPA 650-3-74-006 |
Received from HQ |
AWBERC Library/Cincinnati,OH |
10/04/2023 |
ELBD RPS |
EPA 650-3-74-006 |
repository copy |
AWBERC Library/Cincinnati,OH |
11/17/2014 |
NTIS |
PB-245 046 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
80 pages ; 28 cm |
Abstract |
The purpose of the research reported here was to determine the structure and reactivity of adsorbed oxides of sulfur and other small sulfur-containing molecules. The molecules that were studied include the anion radicals of sulfur dioxide, sulfur trioxide, a triatomic sulfur species and carbonyl sulfide. Diamagnetic sulfate ions, as well as covalently bonded oxides of sulfur, were also studied. The adsorbent was a high surface area magnesium oxide powder. Electron paramagnetic resonance and infrared spectroscopy were used to characterize the surface species. The results show that electronegative molecules such as sulfur dioxide adsorb either by an electron transfer from the solid, forming a negative radical ion, or by reacting with the oxide ions of the lattice. |
Notes |
EPA-650/3-74-006 "August 1974." |
Place Published |
Washington, D.C. |
Title Ser Add Ent |
Ecological research series. |
PUB Date Free Form |
1974 |
Series Title Traced |
Ecological research series |
Series Title Untraced |
Ecological research series\ EPA 650/3-74-006 |
NTIS Prices |
PC A05/MF A01 |
BIB Level |
m |
Medium |
unmediated |
Content |
text |
Carrier |
volume |
Cataloging Source |
OCLC/T |
OCLC Time Stamp |
20141114103813 |
Language |
eng |
Origin |
OCLC |
Type |
MERGE |
OCLC Rec Leader |
01228cam 2200337K 45020 |