Main Title |
Kinetic Studies of the Reduction of Aromatic Azo Compounds in Anaerobic Sediment/Water Systems. |
Author |
Weber, E. J. ;
Wolfe, N. L. ;
|
CORP Author |
Environmental Research Lab., Athens, GA. |
Year Published |
1987 |
Report Number |
EPA/600/J-87/339; |
Stock Number |
PB88-202460 |
Additional Subjects |
Water pollution ;
Azo compounds ;
Aromatic compounds ;
Toxicology ;
Chemical reactivity ;
Reduction(Chemistry) ;
Reprints ;
Chemical kinetics ;
Azobenzene ;
Environmental fate
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB88-202460 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
11p |
Abstract |
The reductive transformation of azobenzene and selected derivatives was investigated in anaerobic sediment/water systems. The azo compounds exhibited pseudo-first-order disappearance kinetics through at least three half-lives. The reduction kinetics of these compounds was studied as a function of their reduction potential and sediment/water distribution coefficient. There was no apparent correlation between the observed disappearance rate constant and reduction potential. Chemical sterilization of the sediment/water sample with formaldehyde and treatment with m-cresol, a dehydrogenase inhibitor, or sodium azide, a metabolic inhibitor, had little effect on the observed reduction rate constants for azobenzene, indicating an abiotic reduction process. Heat sterilization indicated that the reducing agent was heat labile. |
Supplementary Notes |
Pub. in Environmental Toxicology and Chemistry, v6 n12 p911-919 Dec 87. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Kinetic Studies of the Reduction of Aromatic Azo Compounds in Anaerobic Sediment/Water Systems. |
PUB Date Free Form |
1987 |
Category Codes |
57Y; 68D; 99C |
NTIS Prices |
PC A03/MF A01 |
Primary Description |
600/01 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
819623420 |
Origin |
NTIS |
Type |
CAT |