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Grantee Research Project Results

Publications Details for Grant Number GR832373

Synthesis and Application of a New Class of Stabilized Nanoscale Iron Particles for Rapid Destruction of Chlorinated Hydrocarbons in Soil and Groundwater

RFA: Greater Research Opportunities: Research in Nanoscale Science Engineering and Technology (2004)

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Journal Article (19)
Patent/Patent Application (4)
Presentation (12)
Reference Type Citation Progress Report Year Document Sources
Journal Article Bennett P, He F, Zhao D, Aiken B, Feldman L. In situ testing of metallic iron nanoparticle mobility and reactivity in a shallow granular aquifer. Journal of Contaminant Hydrology 2010;116(1-4):35-46. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: Science Direct
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  • Abstract: Science Direct
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  • Other: Science Direct PDF
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Journal Article He F, Zhao D, Liu J, Roberts CB. Stabilization of Fe-Pd nanoparticles with sodium carboxymethyl cellulose for enhanced transport and dechlorination of trichloroethylene in soil and groundwater. Industrial & Engineering Chemistry Research 2007;46(1):29-34. GR832373 (2006)
GR832373 (2007)
GR832373 (Final)
  • Abstract: American Chemical Society-Abstract
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Journal Article He F, Zhao D. Manipulating the size and dispersibility of zerovalent iron nanoparticles by use of carboxymethyl cellulose stabilizers. Environmental Science & Technology 2007;41(17):6216-6221. GR832373 (2007)
GR832373 (Final)
  • Abstract from PubMed
  • Abstract: ACS
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Journal Article He F, Zhao D. Hydrodechlorination of trichloroethene using stabilized Fe-Pd nanoparticles: reaction mechanism and effects of stabilizers, catalysts and reaction conditions. Applied Catalysis B: Environmental 2008;84(3-4):533-540. GR832373 (Final)
  • Abstract: Science Direct abstract
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Journal Article He F, Zhao D. Response to comment on "Manipulating the size and dispersibility of zerovalent iron nanoparticles by use of carboxymethyl cellulose stabilizers." Environmental Science & Technology 2008;42(9):3480. GR832373 (Final)
  • Abstract: ACS
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Journal Article He F, Liu JC, Roberts CB, Zhao D. One-step "green" synthesis of Pd nanoparticles of controlled size and their catalytic activity for trichloroethene hydrodechlorination. Industrial & Engineering Chemistry Research 2009;48(14):6550-6557. GR832373 (Final)
  • Abstract: ACS abstract
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Journal Article He F, Zhang M, Qian T, Zhao D. Transport of carboxymethyl cellulose stabilized iron nanoparticles in porous media: column experiments and modeling. Journal of Colloid and Interface Science 2009;334(1):96-102. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: ScienceDirect PDF
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  • Abstract: Science Direct
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Journal Article Joo SH, Zhao D. Destruction of lindane and atrazine using stabilized iron nanoparticles under aerobic and anaerobic conditions: effects of catalyst and stabilizer. Chemosphere 2008;70(3):418-425. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: ScienceDirect PDF
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  • Abstract: Science Direct
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Journal Article Kanel SR, Goswami RR, Clement TP, Barnett MO, Zhao D. Two dimensional transport characteristics of surface stabilized zero-valent iron nanoparticles in porous media. Environmental Science & Technology 2008;42(3):896-900. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: Auburn University PDF
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  • Abstract: ES&T
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Journal Article Liu J, He F, Durham E, Zhao D, Roberts CB. Polysugar-stabilized Pd nanoparticles exhibiting high catalytic activities for hydrodechlorination of environmentally deleterious trichloroethylene. Langmuir 2008;24(1):328-336. GR832373 (Final)
  • Abstract from PubMed
  • Abstract: ACS abstract
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Journal Article Liu JC, He F, Gunn TM, Zhao D, Roberts CB. Precise seed-mediated growth and size-controlled synthesis of palladium nanoparticles using a green chemistry approach. Langmuir 2009;25(12):7116-7128. GR832373 (Final)
  • Abstract from PubMed
  • Abstract: ACS
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Journal Article Liu R, Zhao D. In situ immobilization of Cu(II) in soils using a new class of iron phosphate nanoparticles. Chemosphere 2007;68(10):1867-1876. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: ScienceDirect PDF
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  • Abstract: Science Direct
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Journal Article Liu R, Zhao D. Reducing leachability and bioaccessibility of lead in soils using a new class of stabilized iron phosphate nanoparticles. Water Research 2007;41(12):2491-2502. GR832373 (2007)
  • Full-text: Science Direct
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  • Abstract: Science Direct
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  • Other: Science Direct
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Journal Article Pan G, Li L, Zhao D, Chen H. Immobilization of non-point phosphorus using stabilized magnetite nanoparticles with enhanced transportability and reactivity in soils. Environmental Pollution 2010;158(1):35-40. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: ScienceDirect PDF
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  • Abstract: Science Direct
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Journal Article Xiong Z, Zhao D, Pan G. Rapid and complete destruction of perchlorate in water and ion-exchange brine using stabilized zero-valent iron nanoparticles. Water Research 2007;41(15):3497-3505. GR832373 (2007)
GR832373 (Final)
  • Abstract from PubMed
  • Full-text: Science Direct-Full Text HTML
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  • Abstract: Science Direct-Abstract
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  • Other: Science Direct-Full Text PDF
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Journal Article Xiong Z, He F, Zhao D, Barnett MO. Immobilization of mercury in sediment using stabilized iron sulfide nanoparticles. Water Research 2009;43(20):5171-5179. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: Science Direct PDF
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  • Abstract: Science Direct
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  • Other: Science Direct HTML
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Journal Article Xiong Z, Zhao D, Pan G. Rapid and controlled transformation of nitrate in water and brine by stabilized iron nanoparticles. Journal of Nanoparticle Research 2009;11(4):807-819. GR832373 (Final)
  • Full-text: Springerlink HTML
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  • Abstract: SpringerLink abstract
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Journal Article Xu Y, Zhao D. Reductive immobilization of chromate in water and soil using stabilized iron nanoparticles. Water Research 2007;41(10):2101-2108. GR832373 (Final)
  • Abstract from PubMed
  • Full-text: ScienceDirect PDF
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  • Abstract: ScienceDirect-Abstract
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Journal Article Zhang M, Wang Y, Zhao D, Pan G. Immobilization of arsenic in soils by stabilized nanoscale zero-valent iron, iron sulfide (FeS), and magnetite (Fe3O4) particles. Chinese Science Bulletin 2010;55(4-5):365-372. GR832373 (Final)
  • Abstract: Chinese Science Bulletin
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Patent/Patent Application Roberts CB, McLeod MC, Anand M. Selection and deposition of nanoparticles using CO2-expanded liquids. Patent No. 7,384,879, June 10, 2008. GR832373 (Final)
  • Abstract: Patent Buddy-Abstract
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Patent/Patent Application Zhao D, Xu Y. In situ remediation of inorganic contaminants using stabilized zero-valent iron nanoparticles. Patent No. 7,635,236 B2, December 22, 2009. GR832373 (Final)
R831431 (Final)
  • Abstract: Google Patents-Abstract
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Patent/Patent Application Zhao D, Xiong Z, Barnett M, Liu R, Harper WF, He F. In situ immobilization of metals in contaminated sites using stabilized iron phosphate nanoparticles. U.S. Patent 7,581,902, September 1, 2009. GR832373 (Final)
  • Abstract: Google Patents-Abstract
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Patent/Patent Application Zhao D, He F. Preparation and applications of stabilized iron nanoparticles for dechlorination of chlorinated hydrocarbons in soils, sediments, and ground water. Patent No. 7,887,880, February 15, 2011. GR832373 (Final)
R831431 (Final)
  • Abstract: Google Patents-Abstract
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Presentation Bennett PJ, Feldman L, He F, Zhao D. Field preparation and testing of “stabilized” reactive bi-metallic nanoparticles composed of iron and palladium. Oral presentation and abstract published, The 16th Annual AEHS Meeting & West Coast Conference on Soils, Sediments and Water, March 13-16, 2006. GR832373 (2006)
not available
Presentation Bennett PJ, Feldman L, He F, Zhao D. Field preparation and testing of “stabilized” reactive bi-metallic nanoparticles composed of iron and palladium. Presented at the 17th Annual AEHS Meeting & West Coast Conference on Soils, Sediments, and Water, San Diego, CA, March 19-22, 2007. GR832373 (2007)
not available
Presentation He F, Xu Y, Liu R, Zhao D. Preparation and application of stabilized nanomaterials for environmental clean-up applications. Presented at the Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China, July 2006 (invited seminar). GR832373 (2006)
GR832373 (2007)
not available
Presentation He F, Zhao D. Application of a new class of polysaccharide-stabilized Fe-Pd nanoparticles for rapid destruction of chlorinated hydrocarbons in water. Presented at the IWA World Water Congress 2006, Beijing, China, September 10-14, 2006. GR832373 (2006)
GR832373 (2007)
not available
Presentation He F, Zhao D, et al. Effects of stabilizers and synthesizing conditions on the reactivity and transportability of Fe-Pd nanoparticles for enhanced dechlorination of trichloroethene in water. Presented at the 232nd ACS National Meeting and Exposition, San Francisco, CA, September 10-14, 2006. GR832373 (2006)
GR832373 (2007)
not available
Presentation He F, Xu Y, Liu R, Zhao D. Preparation and application of stabilized nanomaterials for in situ immobilization of toxic metals in soils and groundwater. Invited Seminar, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China, July 2006. GR832373 (2006)
not available
Presentation He F, Zhao D. Stabilization of Fe-Pd nanoparticles with polysaccharides for enhanced dechlorination of trichloroethylene and soil transportability. Presented at the 2006 Alabama Water Resources Association Conference, Orange Beach, AL, 2006. GR832373 (2007)
not available
Presentation Joo SH, Zhao D. Degradation of chlorinated pesticides using stabilized nanoscale zero-valent iron nanoparticles under aerobic and anaerobic conditions. Presented at the 22nd International Conference on Soils, Sediments and Water, AEHS, University of Massachusetts at Amherst, MA, October 16-19, 2006. GR832373 (2006)
GR832373 (2007)
not available
Presentation Xiong Z, Zhao D. Destruction of perchlorate in water and brine using stabilized zero-valent iron nanoparticles. Oral presentation and extended abstract published, 231st ACS National Meeting, Atlanta, GA, March 26-30, 2006. GR832373 (2006)
not available
Presentation Zhao D, et al. Development and application of novel nanomaterials for environmental cleanup. Presented at the Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China, June 2006 (invited seminar). GR832373 (2007)
not available
Presentation Zhao D, et al. Development and application of novel nanotechnologies for in situ remediation of contaminated soils and groundwater. Presented at the Taiyuan University of Technology, Taiyuan, Shanxi, China, June 2006 (invited seminar). GR832373 (2007)
not available
Presentation Zhao D. Emerging technologies for removal of trace contaminants from water and for soil remediation. Presented at the Texas Tech University, Lubbock, TX, September 22, 2006 (invited seminar). GR832373 (2007)
not available

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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.

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