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Grantee Research Project Results

2008 Progress Report: The Impact of Aerosols, Clouds, and Ozone on Surface UV and Photochemistry in Houston, TX

EPA Grant Number: R833225
Title: The Impact of Aerosols, Clouds, and Ozone on Surface UV and Photochemistry in Houston, TX
Investigators: Lefer, Barry , Slusser, James
Current Investigators: Lefer, Barry , Slusser, James , Byun, Daewon , Rappenglueck, Bernhard , Chellam, Shankar
Institution: University of Houston , Colorado State University
EPA Project Officer: Chung, Serena
Project Period: March 15, 2007 through March 14, 2009 (Extended to March 14, 2011)
Project Period Covered by this Report: March 15, 2008 through March 14,2009
Project Amount: $292,310
RFA: Implications of Tropospheric Air Pollution for Surface UV Exposures (2005) RFA Text |  Recipients Lists
Research Category: Climate Change , Air Quality and Air Toxics , Air

Objective:

To examine how changes in tropospheric pollution affect surface UV levels and ozone photochemistry. In
addition we will investigate the impact of clouds surface UV and ozone photochemistry. Finally, we are
interested in how changes in surface UV due tropospheric pollution compare to those cause by variations in the total column ozone. Based on our previous measurements in Houston from the TexAQS-2000 experiment, we hypothesize that significant reductions in surface UV levels occur in Houston due to tropospheric pollution, primarily from the absorption of UV radiation by aerosols. And that the combined effect of tropospheric pollution and clouds are to significantly suppress photochemical ozone formation in Houston. We predict that changes in UV levels due to tropospheric pollution are of similar magnitude compared to those from total ozone column changes.

Progress Summary:

1. Work status:

The UH-Atmospheric Radiation tower facility in Houston has made use a suite of solar instruments to measure total and diffuse solar UV irradiance at multiple wavelengths with a UV multiple filter rotating shadowband radiometers (UV-MFR and MFR). In addition, the direct solar beam irradiance at multiple wavelengths was monitored with a CIMEL sunphotometer and an EPA single pass Brewer spectrometer. The solar UV actinic flux density was measured with an NCAR scanning double actinic flux spectroradiometer (SAFS) during intensive field operations and with a diode array actinic flux spectrograph (Metcon USA) continuously. A Total Sky Imager (YES Inc) and/or a hemispheric field of view Skycam (Metcon USA ) were used to continuously document cloud cover. The data from this suite of instruments was used to calculate aerosol optical depth, aerosol single scattering albedo, overhead ozone column, and 23 different photolysis frequencies. The NCAR TUV radiative transfer model was used to compare the measurements to estimates of the cloud free and background aerosol conditions. The NASA time dependent photochemical box model was used to examine the impact the changes in surface UV on ozone photochemistry, particularly during the intensive monitoring periods.

A 2-year database of surface UV radiation measurements, atmospheric composition, meteorological data, and sky condition has been compiled and has been used to examine the relative importance of aerosols, clouds, and ozone on surface UV levels and ozone photochemistry in Houston . 

 

 

2. Work progress:

There were two large data gaps during 2008-09 data sampling period, one in the UV-B monitoring instrumentation and the other in the CIMEL sunphotometer. The UV-B monitoring instrumentation was damaged during Hurricane Ike when 90+ mile per hour winds on the roof of Moody Tower resulted in the building grounding cable becoming unattached and subsequently slammed into UV-B monitoring instrumentation. With the hurricane approaching we removed the Brewer and Cimel instrumentation, but the USDA UV-B monitoring scientists advised us that it would be interesting to try to get data during the hurricane. As a result these instruments went back to Colorado State in Fort Collins to be rebuilt and then were sent to the NOAA Central UV Calibration Facility in Boulder to be re-calibrated with FEL 1000W lamps. The instruments then spent approximately 2 months at the NOAA Table Mountain monitoring station so the angular response of the repaired instruments could be re-evaluated and intercompared to the instruments there.

The UH CIMEL sunphotometer was sent back to NASA GSFC for its’ annual calibration in early May, unfortunately most of the AERONET team was away on an extended field campaign in Africa . We did not get the CIMEL back until mid-June, after they were back and had a chance catchup with the backlog of instruments that needed calibrating. Otherwise, we have been fortunate that the other measurements have proceeded quite well with only minimal data loss. The data analysis of the intensive TexAQS II period has resulted in several papers related to UV photochemistry and aerosols.

Future Activities:

We hope this research will provide data that are useful to the air quality forecast community whose models currently do not have adequate cloud and tropospheric pollution feedbacks. In addition, we will compare our results to future campaigns in 2009-10 in Houston, Michigan, and Los Angeles .

 

 

 

 

 


Journal Articles on this Report : 9 Displayed | Download in RIS Format

Publications Views
Other project views: All 38 publications 33 publications in selected types All 33 journal articles
Publications
Type Citation Project Document Sources
Journal Article Chen S, Ren X, Mao J, Chen Z, Brune WH, Lefer B, Rappengluck B, Flynn J, Olson J, Crawford JH. A comparison of chemical mechanisms based on TRAMP-2006 field data. Atmospheric Environment 2010;44(33):4116-4125. R833225 (2008)
R833225 (Final)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: University of Huston - PDF
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  • Journal Article Flynn J, Lefer B, Rappengluck B, Leuchner M, Perna R, Dibb J, Ziemba L, Anderson C, Stutz J, Brune W, Ren X, Mao J, Luke W, Olson J, Chen G, Crawford J. Impact of clouds and aerosols on ozone production in Southeast Texas. Atmospheric Environment 2010;44(33):4126-4133. R833225 (2007)
    R833225 (2008)
    R833225 (Final)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: University of Houston - PDF
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  • Journal Article Luke WT, Kelley P, Lefer BL, Flynn J, Rappengluck B, Leuchner M, Dibb JE, Ziemba LD, Anderson CH, Buhr M. Measurements of primary trace gases and NOY composition in Houston, Texas. Atmospheric Environment 2010;44(33):4068-4080. R833225 (2008)
    R833225 (Final)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: University of Huston - PDF
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  • Journal Article Mao J, Ren X, Chen S, Brune WH, Chen Z, Martinez M, Harder H, Lefer B, Rappengluck B, Flynn J, Leuchner M. Atmospheric oxidation capacity in the summer of Houston 2006: comparison with summer measurements in other metropolitan studies. Atmospheric Environment 2010;44(33):4107-4115. R833225 (2008)
    R833225 (Final)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: ScienceDirect - PDF
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  • Journal Article McMillan WW, Pierce RB, Sparling LC, Osterman G, McCann K, Fischer ML, Rappengluck B, Newsom R, Turner D, Kittaka C, Evans K, Biraud S, Lefer B, Andrews A, Oltmans S. An observational and modeling strategy to investigate the impact of remote sources on local air quality: a Houston, Texas, case study from the Second Texas Air Quality Study (TexAQS II). Journal of Geophysical Research: Atmospheres 2010;115(D1):D01301. R833225 (2008)
  • Full-text: Wiley - Full Text HTML
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  • Abstract: Wiley - Abstract
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  • Other: Wiley - PDF
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  • Journal Article Morris GA, Ford B, Rappengluck B, Thompson AM, Mefferd A, Ngan F, Lefer B. An evaluation of the interaction of morning residual layer and afternoon mixed layer ozone in Houston using ozonesonde data. Atmospheric Environment 2010;44(33):4024-4034. R833225 (2008)
    R833225 (Final)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: ScienceDirect - PDF
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  • Journal Article Olaguer EP, Rappengluck B, Lefer B, Stutz J, Dibb J, Griffin R, Brune WH, Shauck M, Buhr M, Jeffries H, Vizuete W, Pinto JP. Deciphering the role of radical precursors during the Second Texas Air Quality Study. Journal of the Air & Waste Management Association 2009;59(11):1258-1277. R833225 (2008)
    R833225 (Final)
  • Abstract from PubMed
  • Full-text: Taylor & Francis - PDF
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  • Abstract: Taylor & Francis - Abstract
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  • Other: University of Houston - PDF
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  • Journal Article Wright ME, Atkinson DB, Ziemba L, Griffin R, Hiranuma N, Brooks S, Lefer B, Flynn J, Perna R, Rappengluck B, Luke W, Kelley P. Extensive aerosol optical properties and aerosol mass related measurements during TRAMP/TexAQS 2006 – implications for PM compliance and planning. Atmospheric Environment 2010;44(33):4035-4044. R833225 (2008)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: University of Houston - PDF
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  • Journal Article Ziemba LD, Dibb JE, Griffin RJ, Anderson CH, Whitlow SI, Lefer BL, Rappengluck B, Flynn J. Heterogeneous conversion of nitric acid to nitrous acid on the surface of primary organic aerosol in an urban atmosphere. Atmospheric Environment 2010;44(33):4081-4089. R833225 (2008)
  • Full-text: ScienceDirect - Full Text HTML
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  • Other: ScienceDirect - PDF
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  • Relevant Websites:

    UH Moody Tower CIMEL Data: http://aeronet.gsfc.nasa.gov/ 

     

    UH Moody Tower Brewer Data: http://www.esrl.noaa.gov/gmd/grad/neubrew/

     

    UH Moody Tower UV-B and VIS Data: http://uvb.nrel.colostate.edu/UVB/exit EPA

     

    UH Moody Tower Ozone, Meteorological, and All Sky Images: http://www.hnet.uh.edu/exit EPA

     

    University of Houston Ozonesonde dataserver: http://www.imaqs.uh.edu/ozone/exit EPA

     

     

     

     

     

    Progress and Final Reports:

    Original Abstract
  • 2007 Progress Report
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    The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.

    Project Research Results

    • Final Report
    • 2009
    • 2007 Progress Report
    • Original Abstract
    38 publications for this project
    33 journal articles for this project

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