Main Title |
Semi-Empirical Estimation of Sorption of Hydrophobic Pollutants on Natural Sediments and Soils. |
Author |
Karickhoff, Samuel W. ;
|
CORP Author |
Environmental Research Lab., Athens, GA. |
Year Published |
1981 |
Report Number |
EPA-600/J-81-147; |
Stock Number |
PB82-206020 |
Additional Subjects |
Water pollution ;
Sorption ;
Sediments ;
Soils ;
Chemical equilibrium ;
Solution ;
Reprints ;
Numerical solution
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB82-206020 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
16p |
Abstract |
Methods were developed for estimating the equilibrium sorption behavior of hydrophobic pollutants. At low pollutant concentration (aqueous phase concentrations less than half the solubility), sorption isotherms were linear, reversible, and characterized by a partition coefficient, K(p). Partition coefficients normalized to organic carbon, K(oc)(K(oc)=K(p)/fraction organic carbon), were highly invariant over a set of sediments and soils collected from throughout the nation. Equations for estimating K(oc) from water solubility (including crystal energy) and octanol/water partition coefficients were developed. The predictive equations were tested on literature sorption data and found to estimate measured K(oc)'s generally within a factor of two. |
Supplementary Notes |
Pub. in Chemosphere, v10 n8 p833-846 1981. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Semi-Empirical Estimation of Sorption of Hydrophobic Pollutants on Natural Sediments and Soils. |
PUB Date Free Form |
1981 |
Category Codes |
7D; 68D; 99 |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/01 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
323814958 |
Origin |
NTIS |
Type |
CAT |