Main Title |
Photooxidation of Allyl Chloride. |
Author |
Edney, E. O. ;
Shepson, P. B. ;
Kleindienst, T. E. ;
Corse, E. W. ;
|
CORP Author |
Northrop Services, Inc., Research Triangle Park, NC.;Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab. |
Year Published |
1986 |
Report Number |
EPA-68-02-4033; EPA/600/J-86/383; |
Stock Number |
PB87-209300 |
Additional Subjects |
Allyl chloride ;
Air pollution ;
Irradiation ;
Carcinogens ;
Reaction kinetics ;
Chlorine ;
Ozone ;
Hydroxides ;
Nitrogen oxides ;
Reprints ;
Photooxidation
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB87-209300 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
14p |
Abstract |
The photooxidation of allyl chloride was studied by irradiation either in 100-L Teflon bags or in a 22.7-cu m Teflon smog chamber in the presence of added NOx. In the absence of added hydrocarbons, the reaction involves a Cl atom chain, which leads to a highly reactive system. A reaction mechanism is presented to account for the following photooxidation products: chloroacetaldehyde, formaldehyde, 1,3-dichloroacetone, 3-chloroacrolein, acrolein, glyoxal, chloroperoxyacetylnitrate, and peroxypropenylnitrate. The rate constant for OH reaction with allyl chloride at 298K was measured by a relative rate method under conditions where the Cl atom chain length was small and was found to be kOH = 1.7 x 10 to the minus 11th power cc molecule (-1) sec (-1). (Copyright (c) John Wiley & Sons, Inc.) |
Supplementary Notes |
Pub. in International Jnl. of Chemical Kinetics, v18 p597-608 1986. Sponsored by Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Photooxidation of Allyl Chloride. |
PUB Date Free Form |
c1986 |
Category Codes |
68A |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/09 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
726828607 |
Origin |
NTIS |
Type |
CAT |