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Main Title Nonequilibrium Sorption during Displacement of Hydrophobic Organic Chemicals and (45)Ca through Soil Columns with Aqueous and Mixed Solvents.
Author Nkedi-Kizza, P. ; Brusseau, M. L. ; Rao, P. S. C. ; Hornsby., A. G. ;
CORP Author Florida Univ., Gainesville. Dept. of Soil Science.;Robert S. Kerr Environmental Research Lab., Ada, OK.
Publisher c1989
Year Published 1989
Report Number EPA-R-811144; EPA/600/J-89/183;
Stock Number PB90-140906
Additional Subjects Soil chemistry ; Organic compounds ; Solvents ; Water pollution ; Herbicides ; Calcium ; Cations ; Transport properties ; Diffusion ; Experimental design ; Numerical analysis ; Mass transfer ; Reaction kinetics ; Reprints ; Environmental transport ; Land pollution
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NTIS  PB90-140906 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 8p
Abstract A series of miscible displacement experiments was conducted to investigate the significance of intraorganic matter diffusion as the rate-limiting step in sorption of organic and inorganic solutes during steady water flow in soil columns. Displacement studies were performed using Eustis surface soil and the same soil treated with hydrogen peroxide to reduce soil organic carbon content from 0.2% to <0.01%. Two herbicides (diuron and atrazine) were also displaced with binary solvent mixtures containing varying fractions of methanol and water (0-50% methanol). A bi-continuum nonequilibrium sorption model was used to simulate the measured effluent breakthrough curves obtained by simultaneous displacement of a nonadsorbed tracer (tritiated water), an organic solute (herbicide), and a metal cation ((45)Ca). (Copyright (c) 1989 American Chemical Society.)
Supplementary Notes Pub. in Environmental Science and Technology, v23 n7 p814-820 Jul 89. Sponsored by Robert S. Kerr Environmental Research Lab., Ada, OK.
NTIS Title Notes Journal article.
Title Annotations Reprint: Nonequilibrium Sorption during Displacement of Hydrophobic Organic Chemicals and (45)Ca through Soil Columns with Aqueous and Mixed Solvents.
Category Codes 48E; 99F; 68; 68D; 68E
NTIS Prices PC A02/MF A01
Primary Description 600/15
Document Type NT
Cataloging Source NTIS/MT
Control Number 005320468
Origin NTIS
Type CAT