Abstract |
Tests were conducted at Zimpro, Inc., Rothschild, Wisconsin, to determine the effectiveness of wet air oxidation for destruction of two selected aqueous industrial wastes: coke plant waste and Amiben (herbicide) manufacturing waste. A pilot scale facility was tested for the coke plant waste with less than 6g/1 total solids and 5.5 g/1 Biological Oxygen Demand (BOD5), chemical compounds such as cyanides, phenols and cresols were 99% destroyed; BOD5 and Chemical Oxygen Demand (COD) were reduced by about 90%. The concentration of quinoline was reduced by only 66%. Estimated costs for treating 2,120 cu m/day of coke waste were: $12.3 MM capital investment and $9.90/cu m total operating cost. For the Amiben waste, with 55 g/1 total solids and 31 g/1 BOD5, the test showed greater than 99% destruction of the major organic waste components, dichloronitrobenzoic acids, with about 10% conversion to an intermediate degradation product, dichloronitrobenzene. The BOD5 and COD were reduced by 90% and 82%, respectively. Estimated costs for treating 151 cu m/day of Amiben waste were: $2.2 MM capital investment and $18.00/cu m total operating cost. |