Grantee Research Project Results
Publications Details for Grant Number R833223
Monitoring, Photochemical Fate, and Oxidative Degradation by UV and Solar-based Catalytic Technologies of Cyanotoxins in Freshwater Estuaries
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Reference Type | Citation | Progress Report Year | Document Sources |
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Book Chapter | Pelaez M, Antoniou MG, He X, Dionysiou DD, de la Cruz AA, Tsimeli K, Triantis T, Hiskia A, Kaloudis T, Williams C, Aubel M, Chapman A, Foss A, Khan U, O'Shea KE, Westrick J. Sources and occurrence of cyanotoxins worldwide. Chapter 6. In: Kassinos F, Bester, Kümmerer, eds. Xenobiotics in the Urban Water Cycle. Volume 16, Part I. New York, NY:Springer, 2010, pp. 101-127. |
R833223 (Final) |
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Journal Article | Antoniou MG, Shoemaker JA, de la Cruz AA, Dionysiou DD. Unveiling new degradation intermediates/pathways from the photocatalytic degradation of microcystin-LR. Environmental Science & Technology 2008;42(23):8877-8883. |
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Journal Article | Antoniou MG, Shoemaker JA, de la Cruz AA, Dionysiou DD. LC/MS/MS structure elucidation of reaction intermediates formed during the TiO2 photocatalysis of microcystin-LR. Toxicon 2008;51(6):1103-1118. |
R833223 (2008) R833223 (Final) |
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Journal Article | Antoniou MG, Nicolaou PA, Shoemaker JA, de la Cruz AA, Dionysiou DD. Impact of the morphological properties of thin TiO2 photocatalytic films on the detoxification of water contaminated with the cyanotoxin, microcystin-LR. Applied Catalysis B: Environmental 2009;91(1-2):165-173. |
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Journal Article | Antoniou MG, de la Cruz AA, Dionysiou DD. Degradation of microcystin-LR using sulfate radicals generated through photolysis, thermolysis, and e− transfer mechanisms. Applied Catalysis B: Environmental 2010;96(3-4):290-298. |
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Journal Article | Antoniou MG, de la Cruz AA, Dionysiou DD. Intermediates and reaction pathways from the degradation of microcystin-LR with sulfate radicals. Environmental Science & Technology 2010;44(19):7238-7244. |
R833223 (Final) |
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Journal Article | Chen L, Dionysiou DD, O’Shea K. Complexation of microcystins and nodularin by cyclodextrins in aqueous solution, a potential removal strategy. Environmental Science & Technology 2011;45(6):2293-2300. |
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Journal Article | Choi H, Antoniou MG, Pelaez M, de la Cruz AA, Shoemaker JA, Dionysiou DD. Mesoporous nitrogen-doped TiO2 for the photocatalytic destruction of the cyanobacterial toxin microcystin-LR under visible light irradiation. Environmental Science & Technology 2007;41(21):7530-7535. |
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Journal Article | de la Cruz AA, Antoniou MG, Hiskia A, Pelaez M, Song W, O'Shea KE, He X, Dionysiou DD. Can we effectively degrade microcystins? -- Implications on human health. Anti-Cancer Agents in Medicinal Chemistry 2011;11(1):19-37. |
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Journal Article | Han C, Pelaez M, Likodimos V, Kontos AG, Falaras P, O'Shea K, Dionysiou DD. Innovative visible light-activated sulfur doped TiO2 films for water treatment. Applied Catalysis B: Environmental 2011;107(1-2):77-87. |
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Journal Article | Khan U, Benabderrazik N, Bourdelais AJ, Baden DG, Rein K, Gardinali PR, Arroyo L, O’Shea KE. UV and solar TiO2 photocatalysis of brevetoxins (PbTxs). Toxicon 2010;55(5):1008-1016. |
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Journal Article | Oehrle SA, Southwell B, Westrick J. Detection of various freshwater cyanobacterial toxins using ultra-performance liquid chromatography tandem mass spectrometry. Toxicon 2010;55(5):965-972. |
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Journal Article | Pelaez M, de la Cruz AA, Stathatos E, Falaras P, Dionysiou DD. Visible light-activated N-F-codoped TiO2 nanoparticles for the photocatalytic degradation of microcystin-LR in water. Catalysis Today 2009;144(1-2):19-25. |
R833223 (2008) R833223 (Final) |
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Journal Article | Pelaez M, Falaras P, Likodimos V, Kontos AG, de la Cruz AA, O’Shea K, Dionysiou DD. Synthesis, structural characterization and evaluation of sol-gel-based NF-TiO2 films with visible light-photoactivation for the removal of microcystin-LR. Applied Catalysis B: Environmental 2010;99(3-4):378-387. |
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Journal Article | Pelaez M, de la Cruz AA, O’Shea K, Falaras P, Dionysiou DD. Effects of water parameters on the degradation of microcystin-LR under visible light-activated TiO2 photocatalyst. Water Research 2011;45(12):3787-3796. |
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Journal Article | Song W, Xu T, Cooper WJ, Dionysiou DD, de la Cruz AA, O’Shea KE. Radiolysis studies on the destruction of microcystin-LR in aqueous solution by hydroxyl radicals. Environmental Science & Technology 2009;43(5):1487-1492. |
R833223 (2008) R833223 (Final) |
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Journal Article | Westrick JA, Szlag DC, Southwell BJ, Sinclair J. A review of cyanobacteria and cyanotoxins removal/inactivation in drinking water treatment. Analytical and Bioanalytical Chemistry 2010;397(5):1705-1714. |
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Presentation | Antoniou MG, Pelaez M, Shoemaker JA, Nicolaou PA, de la Cruz AA, Dionysiou DD. TiO2 films for UV and visible light-activated photocatalysis: environmental application in the destruction of microcystin-LR. Presented at the 5th European Meeting on Solar Chemistry and Photocatalysis: Environmental Application, (SPEA 5), Sicily, Italy, October 4-8, 2008. |
R833223 (2008) |
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Presentation | Antoniou MG, Shoemaker JA, de la Cruz AA, Dionysiou DD. Destruction of cyanotoxins by hydroxyl radicals and sulfate radicals:reaction intermediates and pathways. Presented at the Symposium Environmental Science and Technology: A Tribute to William “Bill” Glaze, Division of Environmental Chemistry, 238th American Chemical Society National Meeting (ACS), Washington, DC, August 16-20, 2009 (invited). |
R833223 (Final) |
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Presentation | Antoniou MG, Shoemaker JA, de la Cruz AA, Dionysiou DD. Comparison of reaction intermediates and degradation pathways of microcystin-LR following treatment with hydroxyl and sulfate radicals. Presented at the 14th International Conference on TiO2 Photocatalysis: Fundamentals and Applications, The Conference Center, Niagara Falls, NY, October 5-8, 2009 (invited). |
R833223 (Final) |
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Presentation | Antoniou MG, de la Cruz AA, Dionysiou DD. Application of sulfate radical-based advanced oxidation technologies (SR-AOTs) for the degradation of microcystin-LR. Presented at the 1st International Workshop on Application of Redox Technologies in the Environment (ARTE), Istanbul, Turkey, September 14-15, 2009 (invited). |
R833223 (Final) |
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Presentation | Antoniou MG, Nicolaou PA, de la Cruz AA, Dionysiou DD. Investigation of the reaction intermediates and pathways of microcystin-LR following treatment with sulfate radical-based advanced oxidation technologies. Presented at the 2nd European Conference on Environmental Applications of Advanced Oxidation Processes (EAAOP2), Nicosia, Cyprus, September 7-9, 2009 (invited). |
R833223 (Final) |
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Presentation | Aroche Y, Khan U, O’Shea KE. TiO2 photocatalytic degradation and biological activity analysis of domoic acid. Presented at the 239th American Chemical Society National Meeting, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Presentation | Cardenas M, Jiang W, O’Shea KE. Formation and detection of reactive oxygen species during TiO2 photocatalysis. Presented at the 239th American Chemical Society National Meeting, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Presentation | Cardona M, O’Shea KE. Production of singlet oxygen from water soluble endoperoxides. Presented at the 239th American Chemical Society National Meeting, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Presentation | Chen L, O'Shea KE. Host-guest interactions of cyclodextrins and cyanotoxins. Poster presented at the 237th American Chemical Society (ACS) National Meeting, Division of Environmental Chemistry, Session on General Papers, Salt Lake City, UT, March 22-26, 2009. |
R833223 (2008) |
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Presentation | Dionysiou DD. Advanced oxidation technologies and nanotechnologies for water treatment: fundamentals, development and application in the destruction of cyanobacterial toxins. Presented at the NASA John C. Stennis Space Center, Stennis, MS, April 11, 2008 (invited). |
R833223 (2008) |
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Presentation | Dionysiou DD, Antoniou MG, Pelaez M, Choi H, de la Cruz AA, Shoemaker JA. Application of UV and visible-light activated nanostructured TiO2 catalysts for the destruction of emerging organic contaminants in water. Presented at the Session: Environmental, Health, and Safety Aspects of Engineered Nanomaterials, Division of Analytical Chemistry, 236th American Chemical Society (ACS) National Meeting, Philadelphia, PA, August 17-21, 2008 (invited). |
R833223 (2008) |
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Presentation | Dionysiou DD. Advanced oxidation technologies and nanotechnologies for water treatment: fundamentals, development and application in the destruction of cyanobacterial toxins. Presented at Duke University, Durham, NC, February 5, 2009 (invited). |
R833223 (2008) |
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Presentation | Dionysiou DD. Advanced oxidation technologies and nanotechnologies for water treatment:fundamentals, development and application in the destruction of cyanobacterial toxins. Presented at UV Trojan Technologies, London, Ontario, Canada, March 4, 2009 (invited). |
R833223 (2008) |
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Presentation | Dyble J, Fahnenstiel G, Gossiaux D, Westrick JA, Southwell B. The impacts of cyanoHABs on human health in the Great Lakes through drinking water and fish consumption. Presented at the 14th International Conference on Harmful Algae, Hersonissos, Crete-Greece, November 1-5, 2010. |
R833223 (Final) |
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Presentation | He X, Pelaez M, Dionysiou DD. Degradation of microcystin-LR by UV/H2O2 advanced oxidation process. Poster Presented at the 239th American Chemical Society (ACS) National Meeting, Division of Environmental Chemistry, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Presentation | O’Shea KE. Advanced oxidation of naturally occurring toxins; from arsenic to cyanotoxins. Presented at the Florida State University, Tallahassee, FL, January 7, 2010. |
R833223 (Final) |
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Presentation | O’Shea KE. Degradation and detoxification of cyanotoxins by advanced oxidation. Presented at the University of North Florida, Jacksonville, FL, January 8, 2010. |
R833223 (Final) |
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Presentation | Oehrle S, Westrick J. Detection of various freshwater cyanobacterial toxins using ultra performance liquid chromatography-tandem mass spectrometry, emerging aspects on freshwater harmful cyanobacterial blooms and their effects on drinking water quality. Presented at the U.S. EPA Office of Research and Development, Cincinnati, OH, November 18, 2008. |
R833223 (2008) |
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Presentation | Oehrle S, Westrick J. Detection of various freshwater cyanobacterial toxins using ultra performance liquid chromatography-tandem mass spectrometry. Presented at the American Water Works Association National Meeting, Duke Energy Center, Cincinnati, OH, November 16-20, 2008. |
R833223 (2008) |
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Presentation | O’Shea KE. Advanced oxidation of microcystins, emerging aspects on freshwater harmful cyanobacterial blooms and their effects on drinking water quality. Presented at the U.S. EPA Office of Research and Development, Cincinnati, OH, November 18, 2008. |
R833223 (2008) |
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Presentation | O’Shea KE. Radical oxidation and photolytic transformation of cyanotoxins. Presented at the American Water Works Association National Meeting, Duke Energy Center, Cincinnati, OH, November 16-20, 2008. |
R833223 (2008) |
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Presentation | Pelaez M, de la Cruz AA, Dionysiou DD. Nanostructured TiO2 nanoparticles and films activated under visible light for water purification. Presented at the International Conference on Water, Environment and Health Sciences: The Challenges of Climate Change (ICWEHS), Cholula, Puebla, Mexico, April 13-17, 2009. |
R833223 (2008) R833223 (Final) |
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Presentation | Pelaez M, Antoniou MG, Shoemaker JA, de la Cruz A, Dionysiou DD. Development and environmental application of TiO2 photoassisted processes for water purification: degradation of cyanobacterial toxins. Presented at the 12th EuChemMS International Conference on Chemistry and the Environment (ICCE), Stockholm, Sweden, June 14-17, 2009 (invited). |
R833223 (Final) |
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Presentation | Pelaez M, Antoniou MG, Shoemaker JA, Nicolaou PA, de la Cruz AA, Dionysiou DD. UV and visible photoactivated TiO2 films for the degradation of microcystin-LR in water. Presented at The 2nd International Conference from Nanoparticles and Nanomaterials to Nanodevices and Nanosystems (IC4N), Rhodes, Greece, June 28-July 3, 2009 (invited). |
R833223 (Final) |
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Presentation | Pelaez M, de la Cruz AA, Dionysiou DD. Role of natural water matrix in the photocatalytic degradation of microcystin LR with NF-TiO2 films. Presented at the 237th American Chemical Society (ACS) National Meeting, Division of Industrial & Engineering Chemistry, Session on Nanotechnology and the Environment: Emphasis on Green Nanotechnology, Salt Lake City, UT, March 22-26, 2009. |
R833223 (2008) |
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Presentation | Pelaez M, Falaras P, Likodimos V, Kontos AG, Curell K, Stathatos E, Dionysiou DD. Structural, morphological and optical properties of nanostructured NF-TiO2 films for the photocatalytic degradation of emerging micropollutants in water under visible and solar light. Presented at the 239th American Chemical Society (ACS) National Meeting, Division of Environmental Chemistry, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Presentation | Westrick JA, Southwell B, Dyble-Bressie J, Wyrobek L, Szlag D. Potential cyanotoxin exposure to great lakes communities through drinking water. Presented at the 8th International Conference on Toxic Cyanobacteria, Istanbul, Turkey, August 28-September 4, 2010. |
R833223 (Final) |
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Presentation | Westrick J, Szlag D. Monitoring drinking and recreational waters for freshwater cyanobacteria and their toxins. Presented at the Michigan Environmental Health Association’s 2009 Annual Education Conference, Traverse City, MI, March 19, 2009. |
R833223 (2008) |
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Presentation | Westrick J, Szlag D. Toxin producing algae and their occurrences in the Great Lakes. Emerging issues and technologies in drinking water. Presented at The Research and Technical Practices Committee of the Michigan Section, American Water Works Association (AWWA). Lansing, MI, May 19, 2009. |
R833223 (2008) |
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Presentation | Westrick J. A Great Lakes Cyanotoxin Occurrence Study. Presented at the SETAC North America 30th Annual Meeting, New Orleans, LA, November 19-23, 2009. |
R833223 (Final) |
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Proceedings | Antoniou MG, Shoemaker JA, de la Cruz A, Dionysiou DD. Utilization of mass spectrometry for the identification of reaction intermediates formed during the degradation of the cyanotoxins microcystin-LR and cylindrospermopsin. In: Proceedings of the Division of Environmental Chemistry, the 236th American Chemical Society (ACS) National Meeting, Philadelphia, PA, August 17-20, 2008. |
R833223 (2008) |
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Proceedings | Antoniou MG, Choi H, Shoemaker JA, de la Cruz AA, Dionysiou DD. Intermediates of cyanobacterial toxins with hydroxyl-radical based advanced oxidation technologies (HR-AOTs). In: Proceedings of the 2008 American Water Works Association (AWWA) Annual Conference and Exposition (ACE), Atlanta, GA, June 8-12, 2008. |
R833223 (2008) |
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Proceedings | He X, Pelaez M, Dionysiou DD. Degradation of microcystin-LR by UV/H2O2 advanced oxidation process. In:Proceedings of the Division of Environmental Chemistry, 239th American Chemical Society (ACS) National Meeting, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Proceedings | He X, de la Cruz AA, Dionysiou DD. Destruction of cyanotoxins by UV/H2O2 advanced oxidation process. In: Proceedings of the IOA-IUVA World Congress 2011, Paris, France, May 23-27, 2011. |
R833223 (Final) |
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Proceedings | Pelaez M, de la Cruz AA, Dionysiou DD. Visible light-activated TiO2 photocatalytic films: synthesis, characterization and environmental application for the destruction of microcystin-LR. In: Proceedings of the Division of Environmental Chemistry, 236th American Chemical Society (ACS) National Meeting, Philadelphia, PA, August 17-21, 2008. |
R833223 (2008) |
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Proceedings | Pelaez M, Falaras P, Likodimos V, Kontos AG, Curell K, Stathatos E, Dionysiou DD. Structural, morphological and optical properties of nanostructured NF-TiO2 films for the photocatalytic degradation of emerging micropollutants in water under visible and solar light. In:Proceedings of the Division of Environmental Chemistry, 239th American Chemical Society (ACS) National Meeting, San Francisco, CA, March 21-25, 2010. |
R833223 (Final) |
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Proceedings | Pelaez M, Falaras P, Bandala ER, Dunlop P, Byrne A, de la Cruz AA, Dionysiou DD. TiO2-based enhanced photocatalytic degradation and disinfection of water under solar light irradiation. In: Proceedings of the IOA-IUVA World Congress 2011, Paris, France, May 23-27, 2011. |
R833223 (Final) |
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The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.