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Grantee Research Project Results

Journal Publications Details for Grant Number R832245

Understanding Mechanisms of Green Oxidation Catalysis by Iron-TAML Peroxide Activators

RFA: Targeted Research Grant (2004)

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Journal Article (14)
Reference Type Reference Title Journal Author Citation Progress Report Year Document Sources
Journal Article "Green" oxidation catalysis for rapid deactivation of bacterial spores. ANGEWANDTE CHEMIE INTERNATIONAL EDITION Banerjee D, Markley AL, Yano T, Ghosh A, Berget PB, Minkley Jr EG, Khetan SK, Collins TJ Banerjee D, Markley AL, Yano T, Ghosh A, Berget PB, Minkley Jr EG, Khetan SK, Collins TJ. "Green" oxidation catalysis for rapid deactivation of bacterial spores. Angewandte Chemie International Edition 2006;45(24):3974-3977. R832245 (Final)
  • Abstract from PubMed
  • Full-text: Carnegie Mellon University PDF
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  • Abstract: Wiley
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Journal Article FeIII–TAML-catalyzed green oxidative degradation of the azo dye Orange II by H2O2 and organic peroxides: products, toxicity, kinetics, and mechanisms. GREEN CHEMISTRY Chahbane N, Popescu D-L, Mitchell DA, Chanda A, Lenoir D, Ryabov AD, Schramm K-W, Collins TJ Chahbane N, Popescu D-L, Mitchell DA, Chanda A, Lenoir D, Ryabov AD, Schramm K-W, Collins TJ. FeIII–TAML-catalyzed green oxidative degradation of the azo dye Orange II by H2O2 and organic peroxides: products, toxicity, kinetics, and mechanisms. Green Chemistry 2007;9(1):49-57. R832245 (Final)
  • Abstract: RSC Abstract
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Journal Article High-valent iron complexes with tetraamido macrocyclic ligands: structures, Mossbauer spectroscopy, and DFT calculations. JOURNAL OF INORGANIC BIOCHEMISTRY Chanda A, Popescu D-L, Tiago de Oliveira F, Bominaar EL, Ryabov AD, Munck E, Collins TJ Chanda A, Popescu D-L, Tiago de Oliveira F, Bominaar EL, Ryabov AD, Munck E, Collins TJ. High-valent iron complexes with tetraamido macrocyclic ligands: structures, Mössbauer spectroscopy, and DFT calculations. Journal of Inorganic Biochemistry 2006;100(4):606-619. R832245 (Final)
  • Abstract from PubMed
  • Abstract: Science Direct
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Journal Article Activity-stability parameterization of homogeneous green oxidation catalysts. CHEMISTRY-A EUROPEAN JOURNAL Chanda A, Ryabov AD, Mondal S, Alexandrova L, Ghosh A, Hangun-Balkir Y, Horwitz CP, Collins TJ Chanda A, Ryabov AD, Mondal S, Alexandrova L, Ghosh A, Hangun-Balkir Y, Horwitz CP, Collins TJ. Activity-stability parameterization of homogeneous green oxidation catalysts. Chemistry-A European Journal 2006;12(36):9336-9345. R832245 (Final)
  • Abstract from PubMed
  • Abstract: Wiley
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Journal Article Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Chanda A, Khetan SK, Banerjee D, Ghosh A, Collins TJ Chanda A, Khetan SK, Banerjee D, Ghosh A, Collins TJ. Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators. Journal of the American Chemical Society 2006;128(37):12058-12059. R832245 (Final)
  • Abstract from PubMed
  • Abstract: ACS
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Journal Article (TAML)FeIV=O complex in aqueous solution: synthesis and spectroscopic and computational characterization. INORGANIC CHEMISTRY Chanda A, Shan X, Chakrabarti M, Ellis WC, Popescu DL, Tiago de Oliveira F, Wang D, Que Jr L, Collins TJ, Munck E, Bominaar EL Chanda A, Shan X, Chakrabarti M, Ellis WC, Popescu DL, Tiago de Oliveira F, Wang D, Que Jr. L, Collins TJ, Munck E, Bominaar EL. (TAML)FeIV=O complex in aqueous solution: synthesis and spectroscopic and computational characterization. Inorganic Chemistry 2008;47(9):3669-3678. R832245 (Final)
  • Abstract from PubMed
  • Full-text: ACS Publications Full Text
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  • Abstract: ACS
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  • Other: ACS Publications PDF
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Journal Article Little green molecules. SCIENTIFIC AMERICAN Collins TJ, Walter C Collins TJ, Walter C. Little green molecules. Scientific American 2006;294(3):82-90. R832245 (Final)
  • Abstract from PubMed
  • Full-text: Glatfelter PDF
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  • Abstract: Scientific American
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Journal Article Catalase-peroxidase activity of iron(III)-TAML activators of hydrogen peroxide. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Ghosh A, Mitchell DA, Chanda A, Ryabov AD, Popescu DL, Upham E, Collins TJ Ghosh A, Mitchell DA, Chanda A, Ryabov AD, Popescu DL, Upham EC, Collins GJ, Collins TJ. Catalase-peroxidase activity of iron(III)-TAML activators of hydrogen peroxide. Journal of the American Chemical Society 2008;130(45):15116-15126. R832245 (Final)
  • Abstract from PubMed
  • Abstract: ACS-Abstract
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Journal Article Human pharmaceuticals in the aquatic environment: a challenge to Green Chemistry. CHEMICAL REVIEWS Khetan SK, Collins TJ Khetan SK, Collins TJ. Human pharmaceuticals in the aquatic environment:a challenge to Green Chemistry. Chemical Reviews 2007;107(6):2319-2364. R832245 (Final)
  • Abstract from PubMed
  • Full-text: ACS Publications Full Text
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  • Abstract: ACS
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  • Other: ACS Publications PDF
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Journal Article Attaining control by design over the hydrolytic stability of Fe-TAML oxidation catalysts. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY Polshin V, Popescu D-L, Fischer A, Chanda A, Horner DC, Beach ES, Henry J, Qian Y-L, Horwitz CP, Lente G, Fabian I, Munck E, Bominaar EL, Ryabov AD, Collins TJ Polshin V, Popescu D-L, Fischer A, Chanda A, Horner DC, Beach ES, Henry J, Qian Y-L, Horwitz CP, Lente G, Fabian I, Munck E, Bominaar EL, Ryabov AD, Collins TJ. Attaining control by design over the hydrolytic stability of Fe-TAML oxidation catalysts. Journal of the American Chemical Society 2008;130(13):4497-4506. R832245 (Final)
  • Abstract from PubMed
  • Full-text: ACS Publications Full Text
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  • Abstract: ACS
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  • Other: ACS Publications PDF
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Journal Article Thermodynamic, electrochemical, high-pressure kinetic, and mechanistic studies of the formation of oxo Fe(iv)-TAML species in water. INORGANIC CHEMISTRY Popescu DL, Vrabel M, Brausam A, Madsen P, Lente G, Fabian I, Ryabov AD, van Eldik R, Collins TJ Popescu DL, Vrabel M, Brausam A, Madsen P, Lente G, Fabian I, Ryabov AD, van Eldik R, Collins TJ. Thermodynamic, electrochemical, high-pressure kinetic, and mechanistic studies of the formation of oxo FeIV-TAML species in water. Inorganic Chemistry 2010;49(24):11439-11448. R832245 (Final)
  • Abstract from PubMed
  • Abstract: ACS-Abstract
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Journal Article High-valent first-row transition-metal complexes of tetraamido (4NN/2O) ligands: synthesis, structure, and magnetochemistry. COORDINATION CHEMISTRY REVIEWSEM. 2008;252(18-20):2050-2071. Popescu D-L, Chanda A, Stadler M, Tiago de Oliveira F, Ryabov AD, Munck E, Bominaar EL, Collins TJ Popescu D-L, Chanda A, Stadler M, Tiago de Oliveira F, Ryabov AD, Munck E, Bominaar EL, Collins TJ. High-valent first-row transition-metal complexes of tetraamido (4N) and diamidodialkoxido or diamidophenolato (2N/2O) ligands: synthesis, structure, and magnetochemistry. Coordination Chemistry Reviews 2008;252(18-20):2050-2071. R832245 (Final)
  • Abstract: ScienceDirect-Abstract
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Journal Article Destruction of estrogens using Fe-TAML/peroxide catalysis. ENVIRONMENTAL SCIENCE & TECHNOLOGY Shappell NW, Vrabel MA, Madsen PJ, Harrington G, Billey LO, Hakk H, Larsen GL, Beach ES, Horwitz CP, Ro K, Hunt PG, Collins TJ Shappell NW, Vrabel MA, Madsen PJ, Harrington G, Billey LO, Hakk H, Larsen GL, Beach ES, Horwitz CP, Ro K, Hunt PG, Collins TJ. Destruction of estrogens using Fe-TAML/peroxide catalysis. Environmental Science & Technology 2008;42(4):1296-1300. R832245 (Final)
  • Abstract from PubMed
  • Full-text: USDA PDF
  • Abstract: ES&T
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Journal Article Chemical and spectroscopic evidence for an FeV-oxo complex. SCIENCE Tiago de Oliveira F, Chanda A, Banerjee D, Shan X, Mondal S, Que Jr L, Bominaar EL, Munck E, Collins TJ Tiago de Oliveira F, Chanda A, Banerjee D, Shan X, Mondal S, Que Jr. L, Bominaar EL, Munck E, Collins TJ. Chemical and spectroscopic evidence for an FeV-oxo complex. Science 2007;315(5813):835-838. R832245 (Final)
  • Abstract from PubMed
  • Abstract: Science
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