Grantee Research Project Results
Publications Details for Grant Number R832245
Understanding Mechanisms of Green Oxidation Catalysis by Iron-TAML Peroxide Activators
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Reference Type | Citation | Progress Report Year | Document Sources |
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Journal Article | Banerjee D, Markley AL, Yano T, Ghosh A, Berget PB, Minkley Jr EG, Khetan SK, Collins TJ. "Green" oxidation catalysis for rapid deactivation of bacterial spores. Angewandte Chemie International Edition 2006;45(24):3974-3977. |
R832245 (Final) |
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Journal Article | Chahbane N, Popescu D-L, Mitchell DA, Chanda A, Lenoir D, Ryabov AD, Schramm K-W, Collins TJ. FeIII–TAML-catalyzed green oxidative degradation of the azo dye Orange II by H2O2 and organic peroxides: products, toxicity, kinetics, and mechanisms. Green Chemistry 2007;9(1):49-57. |
R832245 (Final) |
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Journal Article | Chanda A, Popescu D-L, Tiago de Oliveira F, Bominaar EL, Ryabov AD, Munck E, Collins TJ. High-valent iron complexes with tetraamido macrocyclic ligands: structures, Mössbauer spectroscopy, and DFT calculations. Journal of Inorganic Biochemistry 2006;100(4):606-619. |
R832245 (Final) |
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Journal Article | Chanda A, Ryabov AD, Mondal S, Alexandrova L, Ghosh A, Hangun-Balkir Y, Horwitz CP, Collins TJ. Activity-stability parameterization of homogeneous green oxidation catalysts. Chemistry-A European Journal 2006;12(36):9336-9345. |
R832245 (Final) |
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Journal Article | Chanda A, Khetan SK, Banerjee D, Ghosh A, Collins TJ. Total degradation of fenitrothion and other organophosphorus pesticides by catalytic oxidation employing Fe-TAML peroxide activators. Journal of the American Chemical Society 2006;128(37):12058-12059. |
R832245 (Final) |
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Journal Article | Chanda A, Shan X, Chakrabarti M, Ellis WC, Popescu DL, Tiago de Oliveira F, Wang D, Que Jr. L, Collins TJ, Munck E, Bominaar EL. (TAML)FeIV=O complex in aqueous solution: synthesis and spectroscopic and computational characterization. Inorganic Chemistry 2008;47(9):3669-3678. |
R832245 (Final) |
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Journal Article | Collins TJ, Walter C. Little green molecules. Scientific American 2006;294(3):82-90. |
R832245 (Final) |
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Journal Article | Ghosh A, Mitchell DA, Chanda A, Ryabov AD, Popescu DL, Upham EC, Collins GJ, Collins TJ. Catalase-peroxidase activity of iron(III)-TAML activators of hydrogen peroxide. Journal of the American Chemical Society 2008;130(45):15116-15126. |
R832245 (Final) |
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Journal Article | Khetan SK, Collins TJ. Human pharmaceuticals in the aquatic environment:a challenge to Green Chemistry. Chemical Reviews 2007;107(6):2319-2364. |
R832245 (Final) |
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Journal Article | Polshin V, Popescu D-L, Fischer A, Chanda A, Horner DC, Beach ES, Henry J, Qian Y-L, Horwitz CP, Lente G, Fabian I, Munck E, Bominaar EL, Ryabov AD, Collins TJ. Attaining control by design over the hydrolytic stability of Fe-TAML oxidation catalysts. Journal of the American Chemical Society 2008;130(13):4497-4506. |
R832245 (Final) |
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Journal Article | Popescu DL, Vrabel M, Brausam A, Madsen P, Lente G, Fabian I, Ryabov AD, van Eldik R, Collins TJ. Thermodynamic, electrochemical, high-pressure kinetic, and mechanistic studies of the formation of oxo FeIV-TAML species in water. Inorganic Chemistry 2010;49(24):11439-11448. |
R832245 (Final) |
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Journal Article | Popescu D-L, Chanda A, Stadler M, Tiago de Oliveira F, Ryabov AD, Munck E, Bominaar EL, Collins TJ. High-valent first-row transition-metal complexes of tetraamido (4N) and diamidodialkoxido or diamidophenolato (2N/2O) ligands: synthesis, structure, and magnetochemistry. Coordination Chemistry Reviews 2008;252(18-20):2050-2071. |
R832245 (Final) |
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Journal Article | Shappell NW, Vrabel MA, Madsen PJ, Harrington G, Billey LO, Hakk H, Larsen GL, Beach ES, Horwitz CP, Ro K, Hunt PG, Collins TJ. Destruction of estrogens using Fe-TAML/peroxide catalysis. Environmental Science & Technology 2008;42(4):1296-1300. |
R832245 (Final) |
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Journal Article | Tiago de Oliveira F, Chanda A, Banerjee D, Shan X, Mondal S, Que Jr. L, Bominaar EL, Munck E, Collins TJ. Chemical and spectroscopic evidence for an FeV-oxo complex. Science 2007;315(5813):835-838. |
R832245 (Final) |
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Presentation | Banerjee D, Ryabov AD, Collins TJ. Understanding the nature of reactive intermediates in the mechanism of oxidation of thioanisoles with Fe-TAML-activators of peroxides. Presented at the 232nd American Chemical Society (ACS) National Meeting, San Francisco, CA, September 10-14, 2006. |
R832245 (Final) |
not available |
Presentation | Chanda A, Tiago de Oliveira F, Bominaar E, Munck E, Collins TJ. Structure, bonding, and electronic properties of Fe(III) and oxo-bridged dimeric Fe(IV) complexes of TetraAmido Macrocyclic Ligand (TAML) systems: experimental and density functional studies. Presented at the 232nd American Chemical Society (ACS) National Meeting, San Francisco, CA, September 10-14, 2006. |
R832245 (Final) |
not available |
Presentation | Collins TJ, Popescu DL, Ryabov AD. Kinetic and mechanistic investigation of the reaction between Fe-TAML-activators and peroxides. Presented at the 230th American Chemical Society (ACS) National Meeting, Washington, DC, August 28-September 1, 2005. |
R832245 (Final) |
not available |
Presentation | Collins TJ, Banerjee D, Ryabov AD. Micellar regulation of the activity of Fe-TAML-activators of peroxides in aqueous solutions. Presented at the 230th American Chemical Society (ACS) National Meeting, Washington, DC, August 28-September 1, 2005. |
R832245 (Final) |
not available |
Presentation | Collins TJ, Chanda A, Khetan S. Towards a “green” approach for oxidative destruction of nitroaromatics in aquatic environment. Presented at the 230th American Chemical Society (ACS) National Meeting, Washington, DC, August 28-September 1, 2005. |
R832245 (Final) |
not available |
Presentation | Popescu D-L, Chanda A, Mitchell DA, Chahbane N, Schramm K-W, Lenoir D, Ryabov AD, Collins TJ. FeIII-TAML-catalyzed green oxidative degradation of orange II: kinetic and mechanistic investigation. Presented at the 231st American Chemical Society (ACS) National Meeting, Atlanta, GA, March 26-30, 2006. |
R832245 (Final) |
not available |
Presentation | Popescu D-L, Ryabov AD, Collins TJ. Towards elucidation the mechanism of catalysis by Fe-TAML activators. Presented at the 231st American Chemical Society (ACS) National Meeting, Atlanta, GA, March 26-30, 2006. |
R832245 (Final) |
not available |
The perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.