Grantee Research Project Results
2002 Progress Report: Hazardous Air Pollutant Mixtures: Measuring and Modeling Complex Exposure
EPA Grant Number: R827928Title: Hazardous Air Pollutant Mixtures: Measuring and Modeling Complex Exposure
Investigators: Adgate, John L. , Pratt, Greg , Ramachandran, Gurumurthy , Zhang, Junfeng , Sexton, Ken
Current Investigators: Adgate, John L. , Church, Timothy , Pratt, Greg , Ramachandran, Gurumurthy , Zhang, Junfeng , Sexton, Ken
Institution: University of Minnesota , University of Medicine and Dentistry of New Jersey , Minnesota Pollution Control Agency
Current Institution: University of Minnesota , Minnesota Pollution Control Agency , University of Medicine and Dentistry of New Jersey
EPA Project Officer: Chung, Serena
Project Period: December 20, 1999 through December 19, 2002 (Extended to June 19, 2004)
Project Period Covered by this Report: December 20, 2001 through December 19,2002
Project Amount: $510,012
RFA: Urban Air Toxics (1999) RFA Text | Recipients Lists
Research Category: Air Quality and Air Toxics , Air
Objective:
The proposed research project, which builds on existing U.S. Environmental Protection Agency (Science to Achieve Results Grant R825241: Measurement and Source Apportionment of Human Exposures to Toxic Air Pollutants in the Minneapolis-St. Paul Metropolitan Area) and University of Minnesota-funded studies in the Minneapolis-St. Paul Metropolitan area, has two objectives: (1) to examine the relationships between ambient monitoring (i.e., outdoor central sites), indoor air monitoring, and personal-exposure monitoring for a mixture of selected hazardous air pollutants (HAPs) (i.e., particle-bound metals in the PM2.5 size fraction and volatile organic compounds [VOCs]); and (2) to examine the relationships between ambient modeling results and monitoring results for exposures to VOCs and metals.
In the course of attaining these objectives, this research project will test several related hypotheses, including: (1) central-site measurements of metal concentrations in the PM2.5 fraction provide reasonable estimates (i.e., within a factor of 2) of indoor concentrations for these particle-bound metals; (2) central-site measurements of metal concentrations in the PM2.5 fraction provide reasonable estimates (i.e., within a factor of 2) of personal-exposure concentrations for these particle-bound metals; (3) the variability in personal metals concentrations in the PM2.5 fraction is related to the variability in indoor at-home metals concentrations in the PM2.5 fraction; (4) the variability in personal exposure to metals in the PM2.5 fraction is related to the variability in indoor at-home and personal VOC levels; (5) for the general population of adults, personal-exposure concentrations for a complex mixture of metals and VOCs can be predicted based on time-activity profiles and ambient dispersion modeling of these HAPs; (6) for the general population of adults, the primary sources contributing to indoor and personal exposure to a complex mixture of metals and VOCs can be predicted based on ambient-source apportionment modeling results; and (7) continuous measures of indoor PM2.5 levels can be used to characterize and explain day-to-day variability in 24-hour gravimetric samples.
Progress Summary:
The following tasks have been completed to date: (1) summary statistical analysis of trace-metal concentration data obtained by x-ray fluorescence analysis of the outdoor PM2.5 central site filters; (2) completion of digestion and chemical analysis using high-resolution inductive coupled plasma mass spectroscopy of more than 800 outdoor, indoor, and personal PM2.5 samples; (3) completion of quality assurance of the trace metals analytical results; (4) continued development of an integrated database of all outdoor, indoor, and personal VOC and PM measurements from the HAP study; (5) completion of an updated (1999) VOC emissions inventory and new ambient dispersion modeling of VOC concentrations in the Minneapolis-St. Paul airshed; and (6) completion of an analysis of continuous measures of indoor and outdoor PM2.5 concentrations.
Future Activities:
In the final year of this research project, we will conduct statistical analyses and modeling of the trace metals in the PM2.5 fraction. We will conduct the exposure modeling described in the objectives above, prepare papers for publication in peer-reviewed journals, and produce a final report.
Journal Articles on this Report : 3 Displayed | Download in RIS Format
| Other project views: | All 9 publications | 7 publications in selected types | All 7 journal articles |
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Adgate JL, Ramachandran G, Pratt GC, Waller LA, Sexton K. Spatial and temporal variability in outdoor, indoor, and personal PM2.5 exposure. Atmospheric Environment 2002;36(20):3255-3265. |
R827928 (2002) R827928 (2003) R827928 (Final) R825241 (Final) |
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Adgate JL, Ramachandran G, Pratt GC, Waller LA, Sexton K. Longitudinal variability in outdoor, indoor, and personal PM2.5 exposure in healthy non-smoking adults. Atmospheric Environment 2003;37(7):993-1002. |
R827928 (2002) R827928 (2003) R827928 (Final) R825241 (Final) |
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Pratt GC, Wu CY, Bock D, Adgate JL, Ramachandran G, Stock TH, Morandi M, Sexton K. Comparing air dispersion model predictions with measured concentrations of VOCs in urban communities. Environmental Science & Technology 2004;38(7):1949-1959. |
R827928 (2002) R827928 (2003) R827928 (Final) R825241 (Final) |
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Supplemental Keywords:
air, exposure, toxics, particulates, volatile organic compounds, VOCs, Minnesota, MN, particles, environmental monitoring., RFA, Scientific Discipline, Air, Toxics, Geographic Area, Waste, Ecosystem Protection/Environmental Exposure & Risk, air toxics, Environmental Chemistry, State, Chemistry, Monitoring/Modeling, chemical mixtures, indoor air, tropospheric ozone, 33/50, Biology, monitoring, cumulative exposure, carbon tetrachloride, Minnesota, MN, environmental monitoring, particulate matter, stratospheric ozone, ambient particle properties, chemical characteristics, particulate, Toluene, mass spectrometry, air pollutants, VOCs, benzene, air pollution, Chloroform, analytical chemistry, PM2.5, atmospheric monitoring, indoor air quality, Volatile Organic Compounds (VOCs), air quality, atmospheric chemistry, heavy metalsProgress and Final Reports:
Original AbstractThe perspectives, information and conclusions conveyed in research project abstracts, progress reports, final reports, journal abstracts and journal publications convey the viewpoints of the principal investigator and may not represent the views and policies of ORD and EPA. Conclusions drawn by the principal investigators have not been reviewed by the Agency.