You are here:
DEVELOPMENT OF A CL-IMPREGNATED ACTIVATED CARBON FOR ENTRAINED-FLOW CAPTURE OF ELEMENTAL MERCURY
Citation:
Ghorishi, S. B., R. M. Keeney, S D. Serre**, B K. Gullett*, AND W. S. Jozewicz. DEVELOPMENT OF A CL-IMPREGNATED ACTIVATED CARBON FOR ENTRAINED-FLOW CAPTURE OF ELEMENTAL MERCURY. ENVIRONMENTAL SCIENCE & TECHNOLOGY. American Chemical Society, Washington, DC, 36(20):4454-4459, (2002).
Description:
Efforts to discern the role of an activated carbon's surface functional groups on the adsorption of elemental mercury [Hg(0)] and mercuric chloride demonstrated that chlorine (Cl) impregnation of a virgin activated carbon using dilute solutions of hydrogen chloride leads to increases (by a factor of 2-3) in fixed-bed capture of these mercury species. A commercially available activated carbon (DARCO FGD, NORIT Americas Inc.[FGD]) was Cl-impregnated (Cl-FGD) [5 lb (2.3 kg) per batch] and tested for entrained-flow, short-time-scale capture of Hg(0). In an entrained flow reactor, the Cl-FGD was introduced in Hg(0)-laden flue gases (86 ppb of Hg(0) of varied compositions with gas/solid contact times of about 3-4 s, resulting in significant Hg(0) removal (80-90%), compared to virgin FGD (10-15%). These levels of Hg(0) removal were observed across a wide range of very low carbon-to-mercury weight ratios (1,000 to 5,000). Variation of the natural gas combustion flue gas composition, by doping with nitrogen oxides and sulfur dioxide, and the flow reactor temperature (100-200 deg. C) had minimal effects on Hg(0) removal by the Cl-FGD in these carbon-to-mercury weight ratios. These results demonstrate significant enhancement of activated carbon reactivity with minimal treatment and are applicable to combustion facilities equipped with downstream particulate matter removal such as an electrostatic precipitator.