Science Inventory

THE HYDROVINYLATION AND RELATED REACTIONS: NEW PROTOCOLS AND CONTROL ELEMENTS IN SEARCH OF GREATER SYNTHETIC EFFICIENCY AND SELECTIVITY. (R826120)

Citation:

RajanBabu, T. V., N. Nomura, J. Jin, B. Radetich, H. Park, AND M. Nandi. THE HYDROVINYLATION AND RELATED REACTIONS: NEW PROTOCOLS AND CONTROL ELEMENTS IN SEARCH OF GREATER SYNTHETIC EFFICIENCY AND SELECTIVITY. (R826120). ORGANIC LETTERS. John Wiley & Sons Incorporated, New York, NY, 5:1963-1968, (1999).

Description:

New reaction conditions and stereochemical control elements for heterodimerization between ethylene (or propylene) and functionalized vinyl arenes are highlighted (see equation). For example, an enantioselective version of the hydrovinylation reaction uses [{(allyl)NiBr}2], a noncoordinating counter anion, (bis-CF3-C6H3)4B-, and a hemilabile ligand such as MOP. Other applications include intramolecular cyclization of 1,6-dienes and heterodimerization of norbornene and ethylene.

Record Details:

Record Type: DOCUMENT (JOURNAL/PEER REVIEWED JOURNAL)
Product Published Date: 01/01/1999
Record Last Revised: 12/22/2005
Record ID: 68048

Organization:

U.S. ENVIRONMENTAL PROTECTION AGENCY

OFFICE OF RESEARCH AND DEVELOPMENT

NATIONAL CENTER FOR ENVIRONMENTAL RESEARCH