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USING CERAMIC MEMBRANES TO RECYCLE TWO NONIONIC ALKALINE METAL-CLEANING SOLUTIONS
Citation:
Chen, A. C., N. Stencel, AND T D. Ferguson*. USING CERAMIC MEMBRANES TO RECYCLE TWO NONIONIC ALKALINE METAL-CLEANING SOLUTIONS. JOURNAL OF MEMBRANE SCIENCE 162:219-234, (1999).
Description:
One ZrO2 ultrafilter (0.05 um pore size) and two a-Al2O3 microfilters (0.2 and 0.8 um) were used to remove one synthetic ester oil and two polyalphaolefin-based and two petroleum hydrocarbon-based oils and greases from two nonionic alkaline cleaning solutions (e.g., Turco 4215-NCLT and Daraclean 282). The removal was evaluated using a series of filtraton runs on a bench-scale unit equipped with a tubular crossflow filtration element. The system was operated by closely controlling the permeate flux and the process parameters that influence flux, and by monitoring changes in pressure gradient across membrane. Oil and grease, total alkalinity, and organic additives wer emeasured in the feed, permeate, and retentate samples. The ZrO2 ultrafilter completely removed the oils and greases, and its permeability could be restored up to 75% of the initial value. While allowing passage of almost all inorganic salts, the filter retained almost all surfactant additives. The a-Al2O3 microfilters became fouled progressively during filtration, and therefore, were not recommended for this application.