Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol
Citation:
Carlton, A., H. Pye, K. Baker, AND C. Hennigan. Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol. ENVIRONMENTAL SCIENCE & TECHNOLOGY. American Chemical Society, Washington, DC, 52(16):9254–9265, (2018). https://doi.org/10.1021/acs.est.8b01869
Impact/Purpose:
The National Exposure Research Laboratory (NERL) Computational Exposure Division (CED) develops and evaluates data, decision-support tools, and models to be applied to media-specific or receptor-specific problem areas. CED uses modeling-based approaches to characterize exposures, evaluate fate and transport, and support environmental diagnostics/forensics with input from multiple data sources. It also develops media- and receptor-specific models, process models, and decision support tools for use both within and outside of EPA.
Description:
Atmospheric models that accurately describe the fate and transport of trace species for the right reasons aid in the development of effective air-quality management strategies that safeguard human health. Controllable emissions facilitate the formation of biogenic secondary organic aerosol (BSOA) to enhance the atmospheric fine particulate matter (PM2.5) burden. Previous modeling with the EPA’s Community Multiscale Air Quality (CMAQ) model predicted that anthropogenic primary organic aerosol (POA) emissions had the greatest impact on BSOA. That experiment included formation processes involving semivolatile partitioning but not aerosol liquid water (ALW), a ubiquitous PM constituent. We conduct 17 summertime CMAQ simulations with updated chemistry and evaluate changes in BSOA due to the removal of individual pollutants and source sectors for the contiguous U.S. CMAQ predicts SO2 from electricity generating units, and mobile source NOX emissions have the largest impacts on BSOA. The removal of anthropogenic NOX, SO2, and POA emissions during the simulation reduces the nationally averaged BSOA by 23, 14, and 8% and PM2.5 by 9.2, 14, and 5.3%, respectively. ALW mass concentrations decrease by 10 and 35% in response to the removal of NOX and SO2 emissions. This work contributes chemical insight into ancillary benefits of Federal NOX and SO2 rules that concurrently reduce organic PM2.5 mass.
URLs/Downloads:
DOI: Additional Benefits of Federal Air-Quality Rules: Model Estimates of Controllable Biogenic Secondary Organic Aerosol