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Sorption of Organophosphorus Flame Retardants on Settled Dust
Citation:
Liu, X., M. Allen, AND N. Roache. Sorption of Organophosphorus Flame Retardants on Settled Dust. In Proceedings, 14th International Conference on Indoor Air Quality and Climate, GhentB, July 03 - 08, 2016. International Society of Indoor Air Quality and Climate (ISIAQ), Santa Cruz, CA, 726-731, (2017).
Impact/Purpose:
This work explores the relationship between OPFR concentrations in settled dust and air. The data can be used to determine partitioning of OPFRs between the gas phase and settled dust indoors and to inform strategies to reduce exposure and risk.
Description:
Organophosphorus flame retardants (OPFRs) are widely used as additives in industrial and consumer products such as electrical and electronic products, furniture, plastics, textiles, and building/construction materials. Due to human exposure and potential health effects, OPFRs including tris(2-chloroethyl) phosphate (TCEP), tris(1-chloro-2-propyl) phosphate (TCPP), and tris(1,3-dichloro-2-propyl) phosphate (TDCPP) are EPA Action Plan chemicals for chemical assessments under the Toxic Substances Control Act (TSCA). This work investigated the sorption of these three compounds from the air to settled Arizona Test Dust (ATD) and house dust (HD) in a dual small chamber system. The OPFR exposed dust was analyzed to determine the sorption concentration and sorption rate of OPFRs on the dust. The effect of the composition of the dust on OPFR sorption was evaluated. The results showed that ATD and HD have varied sorption capacity for OPFRs from air.
