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Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction
Sa, S., M. Gawande, A. Velhinho, J. Veiga, N. Bundaleski, J. Triqueiro, A. Tolstogouzov, O. Teodoro, R. Zboril, R. Varma, AND P. Branco. Magnetically recyclable magnetite-palladium (Nanocat-Fe-Pd) nanocatalyst for the Buchwald-Hartwig reaction. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 16(7):3494-3500, (2014).
The immobilization of Pd on magnetite surface afforded (Nanocat-Fe-Pd) using inexpensive precursors and its catalytic role in the Buchwald-Hartwig reaction for arylation of amines and amides was investigated; C-N bond formation was achieved in moderate to excellent yields and the catalyst could be separated and recycled up to five cycles by magnetic decantation without significant loss in yield.
Submitted to Royal Society of Chemistry (RSC) journal, Green Chemistry
Record Details:Record Type: DOCUMENT (JOURNAL/PEER REVIEWED JOURNAL)
Organization:U.S. ENVIRONMENTAL PROTECTION AGENCY
OFFICE OF RESEARCH AND DEVELOPMENT
NATIONAL RISK MANAGEMENT RESEARCH LABORATORY
SUSTAINABLE TECHNOLOGY DIVISION
CLEAN PROCESSES BRANCH