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ANALYTICAL ASSESSMENT OF THE IMPACTS OF PARTIAL MASS DEPLETION IN DNAPL SOURCE ZONES (SAN FRANCISCO, CA)
Citation:
FALTA, R. W., P. C. RAO, N. BASU, A. L. WOOD, C. G. ENFIELD, M. ANNABEL, J. JAWITZ, AND M. GOLTZ. ANALYTICAL ASSESSMENT OF THE IMPACTS OF PARTIAL MASS DEPLETION IN DNAPL SOURCE ZONES (SAN FRANCISCO, CA). Presented at 2004 AGU Fall Meeting, San Francisco, CA, December 12 - 17, 2004.
Impact/Purpose:
To inform the public
Description:
Analytical solutions describing the time-dependent DNAPL source-zone mass and contaminant discharge rate are used as a flux-boundary condition in a semi-analytical contaminant transport model. These analytical solutions assume a power relationship between the flow-averaged source concentration, and the source DNAPL mass; the empirical exponent (G) is a function of the flow field heterogeneity, DNAPL architecture, and the correlation between them. The DNAPL source strength terms can account for partial source remediation, either at time zero, or at some later time after the DNAPL release. The transport model considers advection, retardation, three-dimensional dispersion, and sequential first-order decay/production of several species. A separate solution is used to compute the time-dependent mass of each contaminant in the plume. A series of examples using different values of G show how the benefits of partial DNAPL source remediation can vary with site conditions. In general, when G >1, relatively large short-term reductions in the plume concentrations and mass occur, but the source longevity is not strongly affected. Conversely, when G <1, the short-term reductions in the plume concentrations and mass are smaller, but the source longevity can be greatly reduced. In either case, the source remediation effort is much more effective if it is undertaken at an early time, before much contaminant mass has entered the plume. If the remediation effort is significantly delayed, the leading parts of the plume are not affected by the source remediation, and additional control or remediation of the plume itself is required.