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Sustainable hybrid photocatalysts: titania immobilized on carbon materials derived from renewable and biodegradable resources
Colmenares, J., R. Varma, AND P. Lisowski. Sustainable hybrid photocatalysts: titania immobilized on carbon materials derived from renewable and biodegradable resources. GREEN CHEMISTRY. Royal Society of Chemistry, Cambridge, Uk, 18(21):5736-5750, (2016).
Prepared as a Critical Review for the Royal Society of Chemistry (RSC) journal, Green Chemistry. This review discusses the sustainable use of earth-abundant materials exemplified by Titanium dioxide and carbon.
This review comprises the preparation, properties and heterogeneous photocatalytic applications of TiO2 immobilized on carbon materials derived from earth-abundant, renewable and biodegradable agricultural residues and sea food waste resources. The overview provides key scientific insights into widely used TiO2 supported on carbonaceous materials emanating from biopolymeric materials such as lignin, cellulose, cellulose acetate, bacterial cellulose, bamboo, wood, starch, chitosan and agricultural residues (biochar, charcoal, activated carbon and their magnetic forms, coal fly ash) or seafood wastes namely eggshell, clamshell and fish scales; materials that serve as a support/template for TiO2. Heightened awareness and future inspirational developments for the valorisation of various forms of carbonaceous functional materials is the main objective. This appraisal abridges various strategies available to upgrade renewable carbon-based feedstock via the generation of sustainable TiO2/carbon functional materials and provides remarks on their future prospects. Hopefully, this will stimulate the development of efficient and novel composite photocatalysts and engender the necessary knowledge base for further advancements in greener photocatalytic technologies.