Science Inventory

NITROUS OXIDE EMISSIONS FROM FOSSIL FUEL COMBUSTION

Citation:

Linak*, W, J. McSorley*, R. Hall*, J. Ryan, R Srivastava, J. Wendt, AND J. Mereb. NITROUS OXIDE EMISSIONS FROM FOSSIL FUEL COMBUSTION. JOURNAL OF GEOPHYSICAL RESEARCH 95(D6):7533-7541, (1990).

Impact/Purpose:

Information.

Description:

The role of coal combustion as a significant global source of nitrous oxide (N2O) emissions was reexamined through on-line emission measurements from six pulverized-coal-fired utility boilers and from laboratory and pilot-scale combustors. The full-scale utility boilers yielded direct N2O emission levels of less than 5 ppm. The sub-scale combustor test data were consistent with full-scale data, and also showed N2O emission levels not exceeding 5 ppm, although these levels increased slightly when various combustion modifications to lower NO emissions were employed. These on-line emission measurements are very different from previously published data. The discrepancy is shown to be due to a sampling artifact by which significant quantities of N2O can be produced in sample containers which have been used in establishing the previously employed N2O data base. Consequently, we conclude that N2O emissions bear no direct relationship to NO emissions from these combustion sources, and that this direct source of N2O is negligible. Other indirect routes for the conversion of NO into N2O outside the combustor and other combustion sources not examined by this study, however, cannot be ruled out.

URLs/Downloads:

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NITROUS OXIDE EMISSIONS FROM FOSSIL FUEL COMBUSTION   (PDF,NA pp, 383 KB,  about PDF)

Record Details:

Record Type: DOCUMENT (JOURNAL/PEER REVIEWED JOURNAL)
Product Published Date: 06/01/1990
Record Last Revised: 08/05/2009
OMB Category: Other
Record ID: 128783

Organization:

U.S. ENVIRONMENTAL PROTECTION AGENCY

OFFICE OF RESEARCH AND DEVELOPMENT

NATIONAL RISK MANAGEMENT RESEARCH LABORATORY

AIR POLLUTION PREVENTION AND CONTROL DIVISION

AIR POLLUTION TECHNOLOGY BRANCH