Nitrogen dioxide (NO2) is one of many highly reactive gases collectively referred to as “nitrogen oxides” (NOx), all of which contain nitrogen and oxygen in varying amounts. Direct air emissions of NOx generally comprise a mix of nitric oxide (NO) and NO2, with a ratio in favor of NO. Specific emissions sources of NOx that can affect local air quality include on-road vehicles, airports, railyards, shipping ports, home wood burning, intense industrial and chemical processes, activities for oil and gas development, and wildfires (see Nitrogen Oxides Emissions indicator). Once emitted to the air, NO reacts rapidly in the presence of ozone to form NO2. In fact, in U.S. urban locations, most measured airborne NO2 comes from the reaction of these two precursors, rather than from direct NO2 emissions (U.S. EPA, 2016).
Scientific evidence indicates that short-term NO2 exposures, ranging from 30 minutes to 24 hours, can cause the exacerbation of asthma symptoms, in some cases resulting in emergency room visits or hospital admissions. Additionally, long-term NO2 exposures are likely to have a causal relationship with respiratory effects, based on evidence for development of asthma (U.S. EPA, 2016).
Atmospheric transformation of NOx and other pollutants leads to the formation of nitrogen-bearing particles that can eventually deposit to the surface, causing acidification, nitrogen enrichment, and other ecological effects. Acidification from the deposition resulting from current emission levels causes a cascade of effects that harm susceptible aquatic and terrestrial ecosystems, including slower growth and injury to forests and localized extinction of fishes and other aquatic species (see Acid Deposition indicator). Further, deposition of reactive nitrogen particles along with other non-atmospheric sources (e.g., fertilizers and wastewater) causes a suite of ecological changes within sensitive ecosystems. Examples include increased primary productivity in most nitrogen-limited ecosystems, biodiversity losses, changes in carbon cycling, and eutrophication and harmful algal blooms in freshwater, estuarine, and ocean ecosystems (U.S. EPA, 2008).
This indicator presents ambient NO2 concentrations in parts per billion (ppb) using two averaging times: 1-hour averages to be consistent with the short-term primary National Ambient Air Quality Standard (NAAQS) and annual averages to present trends consistent with the long-term NO2 NAAQS. Trend data are based on measurements from the State and Local Air Monitoring Stations network and from other special purpose monitors. The number and spatial coverage of monitoring sites vary: between 1980 and 2016, 59 monitoring sites in 46 counties nationwide have sufficient data to characterize annual average trends; and between 1978-1980 and 2014-2016, 10 monitoring sites in 10 counties nationwide have sufficient data to characterize 1-hour trends. Trends are displayed for the entire nation and for each EPA Region with monitoring sites with sufficient long-term data.
Trends in 1-hour NO2 concentrations are presented for the 98th percentile of 1-hour daily maximum concentrations, averaged over three consecutive calendar years. All exhibits in this indicator present the NO2 NAAQS as a point of reference. The fact that the national or regional concentrations fall below the standards does not mean that all monitoring sites nationally or in the EPA Region also are below the standards. The indicator displays trends in the number of trend sites nationwide at which NO2 concentrations exceeded the level of the standards, but these statistics are not displayed for the EPA Regions.
The national annual average NO2 concentration in 2016 was 62 percent lower than that recorded in 1980 (Exhibit 1). Also shown on this graph are the 90th and 10th percentiles of NO2 concentrations based on the distribution of annual statistics at the monitoring sites. This provides additional graphical representation of the distribution of measured concentrations across the monitoring sites for a given year. Thus, for each year, the graphic displays the concentration range where 80 percent of measured values occurred. The highest annual average NO2 concentrations are typically found in urban areas. In addition, of the 59 sites used to determine the trend for annual average concentrations (out of 409 total monitoring sites that were operating in 2016), the number reporting NO2 concentrations above the level of the NO2 standard declined from five sites in 1981 to zero sites since 1992 (Exhibit 2). Annual average NO2 levels in all EPA Regions with trend sites have steadily decreased since 1980, with percent reductions over this time ranging from 45 percent in Region 8 to 66 percent in Region 9 (Exhibit 3). The decrease in NO2 concentrations in this indicator is consistent with the decreasing NOx emissions reported in the Nitrogen Oxides Emissions indicator.
The 98th percentile of 1-hour NO2 concentrations also exhibited a downward trend. From 1978-1980 to 2014-2016, the concentrations decreased by 65 percent across the 10 sites with sufficient data (Exhibit 4). Among these sites, the number reporting concentrations above the level of the 2010 1-hour NAAQS decreased from five sites in the 1978-1980 and 1987-1989 time frames to zero sites since 2005 (Exhibit 5).
Because ambient monitoring for NO2 occurs almost exclusively in high-traffic urban areas, the average concentrations presented in this indicator likely may not reflect NO2 concentrations in rural areas. Also, in rural areas, air mass aging could foster greater relative levels of peroxyacetyl nitrate (PAN) and nitric acid which can cause a positive interference in NO2 measurements.
The measurement of NO2 is based on the conversion of NO2 to NO and the subsequent detection of NO using the chemiluminescence technique. Because there are other nitrogen-containing compounds, such as PAN and nitric acid that can be converted to NO, the chemiluminescence technique may overestimate NO2 concentrations due to these interferences. Measurement devices with ultraviolet photolytic converters are less prone to interferences than devices with heated surfaces (or catalysts) upstream of the chemiluminescence detector, but are not in widespread use.
Because of the relatively small number of trend sites in some EPA Regions, the regional trends are subject to greater uncertainty than the national trends. Some EPA Regions with low average concentrations may include areas with high local concentrations, and vice versa. In addition, the 59 trend sites with sufficient data for annual trends are not dispersed uniformly across all states in the EPA Regions. The 59 sites are located in 19 states. In the remaining 31 states, there currently are insufficient long-term NO2 data from monitoring sites to include in this indicator.
To ensure that long-term trends are based on a consistent set of monitoring sites, selection criteria were applied to identify the subset of NO2 monitoring sites with sufficient data to assess trends since 1980. Monitoring sites without sufficient data are not included in the trend analysis. Some excluded monitoring sites reported NO2 concentrations above the level of the NO2 standard over the time frame covered by this indicator. In 2016, however, no monitoring sites in the U.S. measured annual average NO2 concentrations above the level of the NAAQS.
Summary data in this indicator were provided by EPA’s Office of Air Quality Planning and Standards, based on NO2 ambient air monitoring data in EPA’s Air Quality System (U.S. EPA, 2017a) (https://www.epa.gov/aqs). National and regional trends in this indicator are based on the subset of NO2 monitoring stations that have sufficient data to assess trends since 1980.
U.S. EPA (United States Environmental Protection Agency). 2017a. Data from the Air Quality System. Accessed 2017. https://www.epa.gov/aqs.