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RECORD NUMBER: 111 OF 135

OLS Field Name OLS Field Data
Main Title Reactivity of the Carbonate Radical with Aniline Derivatives.
Author Larson, R. A. ; Zepp, R. G. ;
CORP Author Environmental Research Lab., Athens, GA. ;Illinois Univ. at Urbana-Champaign. Inst. for Environmental Studies.
Year Published 1988
Report Number EPA/600/J-88/053;
Stock Number PB88-250808
Additional Subjects Water pollution ; Free radicals ; Carbonates ; Chemical reactions ; Anilines ; Herbicides ; Carcinogens ; Reaction kinetics ; Amines ; Photolysis ; Reprints ; Toxic substances ; Environmental fate
Holdings
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Status
NTIS  PB88-250808 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. 12/29/1988
Collation 12p
Abstract Carbonate radicals generated by the photolysis of H2O2 at 313 nm in aqueous sodium bicarbonate (pH 8.3) solution reacted with substituted aromatic amine derivatives. Particularly fast reactions (second order rate constants of 5 x 10 to the 8th power to 2 x 10 to the 9th power were observed with anilines bearing electron-donating substituents, either on the ring or at the nitrogen atom. The results suggest that carbonate radicals may play a significant role in the removal of some aromatic amines from the aquatic environment, particularly in carbonate-rich waters.
Supplementary Notes Pub. in Environmental Toxicology and Chemistry, v7 n4 p265-274 Apr 88. Prepared in cooperation with Illinois Univ. at Urbana-Champaign. Inst. for Environmental Studies.
NTIS Title Notes Journal article.
Title Annotations Reprint: Reactivity of the Carbonate Radical with Aniline Derivatives.
PUB Date Free Form c1988
Category Codes 99D; 99E; 68D; 68E
NTIS Prices PC A03/MF A01
Primary Description 600/01
Document Type NT
Cataloging Source NTIS/MT
Control Number 831528010
Origin NTIS
Type CAT