Main Title |
Photosolvolysis of 3,4-Dichloroaniline in Water: Evidence for an Aryl Cation Intermediate. |
Author |
Miller, Glenn C. ;
Miille, Michael J. ;
Crosby, Donald G. ;
Sontum, Steven ;
Zepp, Richard G. ;
|
CORP Author |
California Univ., Davis.;Environmental Research Lab., Athens, GA. |
Year Published |
1978 |
Report Number |
EPA-600/J-79-058; |
Stock Number |
PB80-177348 |
Additional Subjects |
Pesticides ;
Water pollution ;
Photolysis ;
Chlorine organic compounds ;
Molecular energy levels ;
Chemical bonds ;
Excitation ;
Reprints ;
Phenol/amino-chloro
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB80-177348 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
7p |
Abstract |
Irradiation of 3,4-dichloroaniline in water (lambda > 290nm) gave 2-chloro-5-aminophenol with a conversion of 78 plus or minus 5%. The photolysis quantum yield at 313nm of 0.05 plus or minus 0.003 was unaffected by cyanide (0.35M) or pH changes between 4 and 12. A MO calculation indicated a large excited singlet state shift in electron density to the carbon undergoing substitution. The reaction is suggested to proceed through an aryl cation intermediate produced by heterolytic cleavage of the meta carbon-chlorine bond. Reaction from the triplet state is not considered likely since neither oxygen nor sorbic alcohol affected the quantum yield. |
Supplementary Notes |
Pub. in Tetrahedron, v35 n15 p1797-1800 1979. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Photosolvolysis of 3,4-Dichloroaniline in Water: Evidence for an Aryl Cation Intermediate. |
PUB Date Free Form |
18 Sep 78 |
Category Codes |
7D; 68E; 68D; 99F |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/01 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
323778417 |
Origin |
NTIS |
Type |
CAT |