Main Title |
Electronic Absorption Spectra of Inorganic and Organic Compounds of Nitrogen: I. Nitrogen Dioxide-Dinitrogen Tetroxide in Solution. |
Author |
Altshulle, Aubrey P. ;
Stephen, Donald ;
Schwa, Carol Meyers ;
|
CORP Author |
Robert A. Taft Sanitary Engineering Center, Cincinnati, Ohio. |
Year Published |
1957 |
Stock Number |
PB-216 680 |
Additional Subjects |
( Spectroscopic analysis ;
Nitrogen dioxide) ;
( Ultraviolet spectra ;
Nitrogen dioxide) ;
Absorption spectra ;
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB-216 680 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
14p |
Abstract |
The electronic absorption spectra for NO2-N2O4 mixtures has been measured in various non-polar and polar solvents. In non-polar solvents the spectra is very similar to NO2-N2O4 mixtures in the gas state. However, in solvents with unshared electron pairs available particularly ethers, esters, ketones and tertiary amines, a complex multi-banded spectra is observed at room temperature. This spectra appears to be characteristic of NO2-N2O4 in those solvents and to be the result of the same electron donor-acceptor type molecular complexes reported previously in the literature at lower temperatures in the solid state. In olefins and n-alkyl amines reactions occur and the products formed are discussed. (Author) |
PUB Date Free Form |
1957, |
Category Codes |
7B; 59G; 59A |
NTIS Prices |
PC A02/MF A01 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
326548584 |
Origin |
NTIS |
Type |
CAT |