Main Title |
Analysis of Technical Chlordane by Gas Chromatography Mass Spectrometry. |
Author |
Sovocool, G. Wayne ;
Lewis, Robert G. ;
Harless, Robert L. ;
Wilson, Nancy K. ;
Zehr., Robert D. ;
|
CORP Author |
Health Effects Research Lab., Research Triangle Park, N.C. Environmental Toxicology Div. |
Year Published |
1977 |
Report Number |
EPA/600/J-77/087; |
Stock Number |
PB-278 593 |
Additional Subjects |
Chlordan ;
Pesticides ;
Chemical analysis ;
Gas chromatography ;
Mass spectroscopy ;
Molecular structure ;
Chlorine organic compounds ;
Cyclopentadiene compounds ;
Reprints ;
Cyclopentadiene/hexachloro ;
Cyclopentadiene/tetrachloro ;
Cyclopentadiene/pentachloro
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB-278 593 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
9p |
Abstract |
The composition of technical chlordane has been investigated by combined gas chromatography/mass spectrometry, employing a column commonly used for pesticide residue analysis. Partial or complete structure identification have been assigned to some 45 individual constituents. Many of these compounds are simple Diels-Alder adducts of cyclopentadiene and hexachlorocyclopentadiene, with further chlorine addition or substitution. Additionally, a series of adducts derived from tetra- and pentachlorocyclopentadiene, followed by further chlorination, has been identified. Several components appear to have incorporated trichloromethyl moieties from the solvent during manufacture. Other compounds with abnormal or rearranged ring fusions have also been recognized and their unusual mass spectra have been studied. |
Supplementary Notes |
Pub. in. Analytical Chemistry, v49 p734-740 1977. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Analysis of Technical Chlordane by Gas Chromatography Mass Spectrometry. |
PUB Date Free Form |
31 Jan 77 |
Category Codes |
7D; 99A; 57P |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/11 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
323736971 |
Origin |
NTIS |
Type |
CAT |