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RECORD NUMBER: 44 OF 265

OLS Field Name OLS Field Data
Main Title Correlations between 31P n.m.r. Chemical Shifts and Structures of Some Organophosphorus Pesticides.
Author Ross, Ralph T. ; Biros., Francis J. ;
CORP Author Environmental Protection Agency, Perrine, Fla. Perrine Primate Lab.
Year Published 1970
Stock Number PB-275 504
Additional Subjects Pesticides ; Chemical analysis ; Phosphorus organic compounds ; Molecular structure ; Phosphorus isotopes ; Reprints ; Chemical shifts(Nuclear magnetic resonance) ; Phosphorus 31
Holdings
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Status
NTIS  PB-275 504 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 06/23/1988
Collation 3p
Abstract Several recent publications have described the usefulness of high-resolution proton magnetic resonance (n.m.r.) for the elucidation of structure of phosphorus-containing organic compounds used as pesticides. Because phosphorus n.m.r. is playing an ever-increasing role in structure characterization and qualitative identification, of phosphorus compounds, the authors have examined (31)P n.m.r. spectra of a series of organophosphorus pesticidal compounds. Chemical shifts for thirty-seven organophosphorus pesticides have been measured and correlated with the structures of nine classes of these compounds. Empirical correlations describing the relative effects which the atoms adjacent to phosphorus have on the chemical shifts are given for some of these classes. These correlations between (31)P n.m.r. shifts and structure are presented for use in qualitative prediction.
Supplementary Notes Pub. in Analytica Chimica Acta, 52 p139-141 1970.
Availability Notes Included in the report, Journal Articles on Pesticide Chemical Analysis. Group 2, PB-275 495.
Title Annotations Reprint: Correlations between 31P n.m.r. Chemical Shifts and Structures of Some Organophosphorus Pesticides,
PUB Date Free Form 29 Apr 70
Category Codes 7D; 6F; 99A; 57P
NTIS Prices (Order as PB-275 495, MF A01)
Primary Description 500/01
Document Type NT
Cataloging Source NTIS/MT
Control Number 323729587
Origin NTIS
Type CAT