Main Title |
Multinuclear NMR Spin Labeling Investigation of the Solution Structure of the Base Stacked Mn(+2) -AMP Complex. |
Author |
Levy, George C. ;
Dechter, James J. ;
|
CORP Author |
Florida State Univ., Tallahassee. Dept. of Chemistry.;Health Effects Research Lab., Research Triangle Park, NC. |
Year Published |
1979 |
Report Number |
EPA-R-804916; EPA-600/J-80-379; |
Stock Number |
PB82-155284 |
Additional Subjects |
Isotopic labeling ;
Nuclear magnetic resonance ;
Molecular structure ;
Nitrogen organic compounds ;
Reprints ;
Adenine/ribofuranosyl ;
Nitrogen 15 ;
Carbon 13 ;
Phosphorus 31
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB82-155284 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
8p |
Abstract |
(15)N, (13)C, and (31)P electron-nuclear relaxation times are used to determine the solution structure of the base stacked Mn(+2) -AMP complex. The nitrogen-Mn(+2) distances that are determined indicate a direct inner-sphere coordination of Mn(+2) at N(1), N(7), and the amino NH2 positions. The phosphorus-Mn(+2) distance also indicates direct coordination and this second site may explain the anomalously short Mn(+2) -C(8) distance that is found. A structure is proposed consistent with the measured distances. Comparison of Mn(+2) -carbon distances with those in the literature is made. |
Supplementary Notes |
Pub. in Jnl. of the American Chemical Society, v102 n20 p6191-6196 1980. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: A Multinuclear NMR Spin Labeling Investigation of the Solution Structure of the Base Stacked Mn(+2) -AMP Complex. |
PUB Date Free Form |
24 Aug 79 |
Category Codes |
7D; 99F |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/11 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
323810765 |
Origin |
NTIS |
Type |
CAT |