Main Title |
Determination of haloethers in industrial and municipal wastewaters / |
Author |
Sherman, Paul L. ;
Kyne, Joseph M. ;
Gable, Roger C. ;
Pustinger, John V. ;
McMillin, Carl R. ;
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Other Authors |
|
CORP Author |
Monsanto Research Corp., Dayton, OH.;Environmental Monitoring and Support Lab., Cincinnati, OH. Physical and Chemical Methods Branch. |
Publisher |
U.S. Environmental Protection Agency, Environmental Monitoring and Support Laboratory ; Available from National Technical Information Service, |
Year Published |
1981 |
Report Number |
EPA-600/4-81-062; PB81232290 |
Stock Number |
PB81-232290 |
OCLC Number |
33374739 |
Subjects |
Haloethers ;
Water--Analysis ;
Factory and trade waste--United States
|
Additional Subjects |
Water analysis ;
Halogen organic compounds ;
Ethers ;
Chemical analysis ;
Industrial wastes ;
Gas chromatography ;
Sewage ;
Extraction ;
Concentration(Composition) ;
Water pollution detection ;
Ether/(chloroethyl)-vinyl ;
Ether/bis(chloroisopropyl) ;
Ether/bis(chloroethyl) ;
Methane/bis(chloroethoxy) ;
Ether/(chlorophenyl)-phenyl ;
Ether/(bromophenyl)-phenyl ;
Ether/dichloro-methyl
|
Internet Access |
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
ELBD ARCHIVE |
EPA 600/4-81-062 |
Received from HQ |
AWBERC Library/Cincinnati,OH |
10/04/2023 |
NTIS |
PB81-232290 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
viii, 70 leaves : ill. ; 28 cm. |
Abstract |
This document describes an analytical method, not based on mass spectrometry, for the analysis of haloethers in water and wastewater. The following haloethers were originally included in this study: 2-chloroethyl vinyl ether, bis(2-chloroisopropyl) ether, bis(2-chloroethyl) ether, bis(2-chloroethoxy) methane, 4-chlorophenyl phenyl ether, 4-bromophenyl phenyl ether, and (bischloromethyl) ether. The 2-chloroethyl vinyl ether and the bis(chloromethyl) ether were later deleted from the project because of extreme volatility and hydrolytic instability, respectively. A literature search was conducted to acquire published information on the hydrolytic stability of the haloethers, methods for the detection of haloethers in water, and method for the isolation, concentration, and analysis of haloethers. Gas chromatography studies were completed to compare different packings for use with haloethers and to compare the results obtained using a Hall electrolytic conductivity detection with those obtained using an electron capture detector. The workable method developed in this program for the analysis of haloethers in wastewater consisted of a liquid/liquid extraction using methylene chloride, an evaporation step using Kunderna-Danish (K-D) evaporators, a column chromatographic cleanup procedure using Florisil, another K-D evaporation of the fraction from the Florisil column, and subsequent analysis by gas chromatography using an electrolytic conductivity detector. |
Notes |
"July 1981." "EPA-600/4-81-062." "PB81-232290." Includes bibliographical references (leaf 59-62). |
Place Published |
Cincinnati, OH Springfield, Va. |
Access Notes |
Also available on the Internet. |
Corporate Au Added Ent |
Environmental Monitoring and Support Laboratory (Cincinnati, Ohio) |
PUB Date Free Form |
1981 |
BIB Level |
m |
Cataloging Source |
OCLC/T |
OCLC Time Stamp |
20090316134119 |
Language |
eng |
Origin |
OCLC |
Type |
MERGE |
OCLC Rec Leader |
01291cam 2200337Ia 45020 |