Main Title |
Volatile Halocarbon Production from the Chlorination of Marine Algal Byproducts, Including D-Mannitol. |
Author |
Crane, Allan M. ;
Kovacic, Peter ;
Kovacic., Eric D. ;
|
CORP Author |
Environmental Research Lab., Gulf Breeze, FL. |
Year Published |
1980 |
Report Number |
EPA-600/J-80-221 ;ERL.GB-J928; |
Stock Number |
PB81-165334 |
Additional Subjects |
Algae ;
Chlorination ;
Water pollution ;
pH ;
Halogen organic compounds ;
Sugar alcohols ;
Glycerol ;
Proline ;
Reprints ;
Isochrysis galbana ;
Thalassiosira pseudonana ;
Carteria ;
Chemical reaction mechanisms
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB81-165334 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
6p |
Abstract |
The ability of various exudates of marine algae to produce chloroform during solution chlorination was investigated. D-Mannitol generated amounts that increased markedly with increase in pH, whereas glycerol under similar conditions yielded little product. L-Proline exerted an inhibiting effect. The mechanism of the D-mannitol reaction is believed to proceed via formation of a ketolactone which undergoes ring opening by chloride, followed by the classical haloform process. |
Supplementary Notes |
Pub. in Environmental Science and Toxicology, v14 n11 p1371-1374 Nov 80. Prepared in cooperation with Wisconsin Univ.-Milwaukee. Dept. of Chemistry and Harvard Univ., Cambridge, MA. Dept. of Chemistry. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Volatile Halocarbon Production from the Chlorination of Marine Algal Byproducts, Including D-Mannitol. |
PUB Date Free Form |
1980 |
Category Codes |
13B; 68D |
NTIS Prices |
PC A02/MF A01 |
Primary Description |
600/04 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
323793276 |
Origin |
NTIS |
Type |
CAT |