Main Title |
Halocarbon Hydrolysis Rates: A Search for Ionic Strength and Heterogenous Effects. |
Author |
Jeffers, P. M. ;
Coty, P. ;
Luczak, S. ;
Wolfe, N. L. ;
|
CORP Author |
Environmental Research Lab., Athens, GA. Office of Research and Development. ;State Univ. of New York Coll. at Cortland. Dept. of Chemistry.;Air Force Civil Engineering Support Agency, Tyndall AFB, FL. |
Publisher |
c1994 |
Year Published |
1994 |
Report Number |
EPA/600/J-94/453; |
Stock Number |
PB95-133120 |
Additional Subjects |
Halohydrocarbons ;
Hydrolysis ;
Water pollution ;
Reprints ;
Ground water ;
Reaction kinetics ;
Hydrogeology ;
Heterogeneity ;
Sea water ;
Environmental persistence ;
Chemical properties ;
Water chemistry ;
Minerals ;
Ionic strength
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB95-133120 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
13p |
Abstract |
Ten chlorinated or fluorinated alkanes and alkenes were hydrolyzed in deionized aqueous solution, in 'sea water,' or in the presence of 11 different crushed solid minerals including sulfides, oxides, hydroxides, and aquifer materials. No changes in the observed hydrolysis rates were found upon changing from a pure water environment to one of high ionic strength or of significant potential heterogeneous catalytic activity for these typical halogenated hydrocarbons. Successive partial substitutions of fluorine for chlorine in the ethanes was shown to retard hydrolysis by one to five orders of magnitude. |
Supplementary Notes |
Pub. in Jnl. of Environmental Science and Health, A29 n4 p821-831 1994. Prepared in cooperation with State Univ. of New York Coll. at Cortland. Dept. of Chemistry. Sponsored by Air Force Civil Engineering Support Agency, Tyndall AFB, FL. |
NTIS Title Notes |
Journal article. |
Title Annotations |
Reprint: Halocarbon Hydrolysis Rates: A Search for Ionic Strength and Heterogenous Effects. |
Category Codes |
68; 68D; 48G; 47C |
NTIS Prices |
PC A03/MF A01 |
Primary Description |
600/01 |
Document Type |
NT |
Cataloging Source |
NTIS/MT |
Control Number |
500619501 |
Origin |
NTIS |
Type |
CAT |