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Main Title Molecular Oxygen and the Adsorption of Phenols: Effect of Functional Groups.
Author Vidic, R. D. ; Suidan, M. T. ; Brenner, R. C. ; Sorial., G. A. ;
CORP Author Environmental Protection Agency, Cincinnati, OH. Risk Reduction Engineering Lab. ;Cincinnati Univ., OH. ;Pittsburgh Univ., PA.
Publisher c1993
Year Published 1993
Report Number EPA/600/A-94/041;
Stock Number PB94-158672
Additional Subjects Oxygenation ; Phenols ; Adsorption ; Granular activated carbon treatment ; Water pollution control ; Polymerization ; Best technology ; Nitro compounds ; Sewage treatment ; Industrial waste treatment ; Performance evaluation ; Extraction ; Isotherms ; Surface chemistry ; Reprints ;
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NTIS  PB94-158672 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 15p
Abstract The study reveals that the presence of molecular oxygen (oxic conditions) has a significant impact on the exhibited adsorptive capacity of granular activated carbon (GAC) for several phenolic compounds. The increase in the GAC adsorptive capacity under oxic condition results from polymarization of these adsorbates on the carbon surface. The mechanism of polymer formation is through oxidative coupling of phenolic molecules. The extent of an increase in the GAC adsorptive capacity is in accordance with the ease of oxidation of these compounds. However, substituting a nitro group on the parent phenol molecule suppressed polymerization reactions, and no increase in the GAC adsorptive capacity was observed under oxic conditions for these substituents.
Supplementary Notes Pub. in Proceedings of the Water Pollution Control Federation Annual Conference and Exposition (64th), Toronto, Ontario, October 7-10, 1991, p1-13. See also PB94-113776. Prepared in cooperation with Cincinnati Univ., OH. and Pittsburgh Univ., PA.
NTIS Title Notes Proceedings 1990-93.
Title Annotations Reprint: Molecular Oxygen and the Adsorption of Phenols: Effect of Functional Groups.
Category Codes 68D; 99C; 99F
NTIS Prices PC A03/MF A01
Primary Description 600/14
Document Type NT
Cataloging Source NTIS/MT
Control Number 414726603
Origin NTIS
Type CAT