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Main Title Halocarbon Hydrolysis Rates: A Search for Ionic Strength and Heterogenous Effects.
Author Jeffers, P. M. ; Coty, P. ; Luczak, S. ; Wolfe, N. L. ;
CORP Author Environmental Research Lab., Athens, GA. Office of Research and Development. ;State Univ. of New York Coll. at Cortland. Dept. of Chemistry.;Air Force Civil Engineering Support Agency, Tyndall AFB, FL.
Publisher c1994
Year Published 1994
Report Number EPA/600/J-94/453;
Stock Number PB95-133120
Additional Subjects Halohydrocarbons ; Hydrolysis ; Water pollution ; Reprints ; Ground water ; Reaction kinetics ; Hydrogeology ; Heterogeneity ; Sea water ; Environmental persistence ; Chemical properties ; Water chemistry ; Minerals ; Ionic strength
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NTIS  PB95-133120 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 13p
Abstract Ten chlorinated or fluorinated alkanes and alkenes were hydrolyzed in deionized aqueous solution, in 'sea water,' or in the presence of 11 different crushed solid minerals including sulfides, oxides, hydroxides, and aquifer materials. No changes in the observed hydrolysis rates were found upon changing from a pure water environment to one of high ionic strength or of significant potential heterogeneous catalytic activity for these typical halogenated hydrocarbons. Successive partial substitutions of fluorine for chlorine in the ethanes was shown to retard hydrolysis by one to five orders of magnitude.
Supplementary Notes Pub. in Jnl. of Environmental Science and Health, A29 n4 p821-831 1994. Prepared in cooperation with State Univ. of New York Coll. at Cortland. Dept. of Chemistry. Sponsored by Air Force Civil Engineering Support Agency, Tyndall AFB, FL.
NTIS Title Notes Journal article.
Title Annotations Reprint: Halocarbon Hydrolysis Rates: A Search for Ionic Strength and Heterogenous Effects.
Category Codes 68; 68D; 48G; 47C
NTIS Prices PC A03/MF A01
Primary Description 600/01
Document Type NT
Cataloging Source NTIS/MT
Control Number 500619501
Origin NTIS
Type CAT