Main Title |
Catalytic dehyrohalogenation : a chemical destruction method for halogentated organics. |
Author |
Harden, J. M. ;
Ramsey, G. G.
|
CORP Author |
Radian Corp., Research Triangle Park, NC.;Environmental Protection Agency, Cincinnati, OH. Hazardous Waste Engineering Research Lab. |
Publisher |
U.S. Environmental Protection Agency, Hazardous Waste Engineering Research Laboratory, |
Year Published |
1986 |
Report Number |
EPA/600/2-86/113; EPA-68-02-3994 |
Stock Number |
PB87-133104 |
Subjects |
Halogenation ;
Elimination reactions ;
Organohalogen compounds ;
Hazardous wastes
|
Additional Subjects |
Hazardous materials ;
Waste disposal ;
Dehydrohalogenation ;
Chemical reactions ;
Halogen organic compounds ;
Chemical reaction kinetics ;
Hazard wastes ;
Toxic substances
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
NTIS |
PB87-133104 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
44 pages ; 28 cm |
Abstract |
Dehydrohalogenation shows potential as a means for converting certain halogenated organics in wastes to inorganic salts and gaseous aliphatic compounds. Dehydrohalogenation is a dehalogenation/elimination reaction that is initiated by a strong base. The resulting products are the halide salt, water, and an elimination compound. A novel reagent, sodium or potassium hydroxide mixed with a polyethylene glycol, is a very effective dehydrohalogenation agent. The reagent is shown to dehalogenate six organic compounds that are representative of low molecular weight compounds encountered in hazardous wastes: CCl4, CHCl3, CH2Cl2, C2H4Br2, and CCl3NO2. Kinetics data for the reactions of the reagent with the six compounds is given to allow reactor design and calculation of destruction efficiency. |
Notes |
Caption title. "December 1986." "EPA/600/2-86/113." Microfiche. |
Place Published |
Cincinnati, OH : |
Supplementary Notes |
Sponsored by Environmental Protection Agency, Cincinnati, OH. Hazardous Waste Engineering Research Lab. |
Corporate Au Added Ent |
Hazardous Waste Engineering Research Laboratory. |
PUB Date Free Form |
{1986} |
NTIS Prices |
PC A03/MF A01 |
BIB Level |
m |
Cataloging Source |
OCLC/T |
OCLC Time Stamp |
20020114185208 |
Language |
eng |
Origin |
NTIS |
Type |
MERGE |
OCLC Rec Leader |
01062nam 2200289Ka 45020 |