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RECORD NUMBER: 339 OF 378

Main Title Surface reactions of oxides of sulfur /
Author Lunsford, J. H.,
Other Authors
Author Title of a Work
Durham, Jack L.,
CORP Author Texas A and M Univ., College Station. Dept. of Chemistry.;Environmental Sciences Research Lab., Research Triangle Park, NC.
Publisher Environmental Sciences Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency,
Year Published 1979
Report Number EPA-600/7-79-088; EPA-R-801136; PB297410
Stock Number PB-297 410
OCLC Number 53915971
Additional Subjects Sulfur oxides ; Surface chemistry ; Air pollution ; Ion exchange resins ; Oxidation ; Sulfur ; Catalysts ; Aerosols ; Oxygen ; Nitrogen dioxide ; Hydrogen sulfide ; Chemical reactions ; Adsorption ; Electron paramagnetic resonance ; Magnesium oxides ; Chemical reaction mechanisms ; Heterogeneous reactions ; Zeolites
Internet Access
Description Access URL
https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=9101K6GC.PDF
Holdings
Library Call Number Additional Info Location Last
Modified
Checkout
Status
EJBD  EPA 600-7-79-088 c.1 Headquarters Library/Washington,DC 03/18/2014
EKBD  EPA-600/7-79-088 Research Triangle Park Library/RTP, NC 12/19/2003
ELBD ARCHIVE EPA 600-7-79-088 Received from HQ AWBERC Library/Cincinnati,OH 10/04/2023
ESAD  EPA 600-7-79-088 Region 10 Library/Seattle,WA 03/23/2010
NTIS  PB-297 410 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation viii, 34 pages : charts ; 28 cm
Abstract Surface reactions of several sulfur-containing molecules have been studied in order to understand the mechanism by which sulfate ions are formed on atmospheric aerosols. At 25C the heterogeneous oxidation of SO2 by NO2 to sulfuric acid and sulfate ions occurred on hydrated silica and silica-alumina surfaces. The oxidation of SO2 by O2 was undetectably slow on these surfaces; however, the reaction was catalyzed by Mn(+2) ions in a Y-type zeolite. In this case the only reaction product was a SO4(-2) species which was strongly bound in the zeolite micropores. Molecular oxygen also reacted with H2S on zeolites and magnesium oxide. The primary reactions on zeolites resulted in the formation of elemental sulfur; whereas, on MgO a variety of products were observed including elemental sulfur, sulfide ions, sulfite ions and a number of paramagnetic ions such as S3(-), S2O(-) and S sub n(-). Experiments were also carried out to identify and to determine the mechanism by which S2O(-) and H2S2(-) are formed on MgO. To establish the geometric structure of the S2O(-) ion and other paramagnetic sulfur-containing molecules on MgO, CNDO semiempirical calculations were carried out to determine theoretical values of g tensors and spin densities as a function of bond angles and bond lengths.
Notes Project Officer: Jack L. Durham. Dept. of Chemistry, Texas A & M University "EPA-600/7-79-088"--Cover "April 1979"--Cover "Grant No. R-801136"--T.p Includes bibliographical references (pages 31-33).
Place Published Research Triangle Park, North Carolina
Access Notes Also available via the World Wide Web
Corporate Au Added Ent United States. Environmental Protection Agency.; United States. Environmental Protection Agency. Office of Research and Development.; Environmental Sciences Research Laboratory.; Texas A & M University. Department of Chemistry.
Corp Au Ser Add Ent United States. Environmental Protection Agency. Interagency energy-environment research and development program report ; EPA-600/7-79-088.
PUB Date Free Form 1979
Series Title Untraced Interagency energy-environment research and development program report ; EPA-600/7-79-088
NTIS Prices PC A03/MF A01
BIB Level m
Medium unmediated
Content text
Carrier volume
Cataloging Source RDA
OCLC Time Stamp 20140313155105
Language eng
Origin OCLC
Type MERGE
OCLC Rec Leader 01865cam 2200409Ki 45020