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Main Title Development and Testing of a Surrogate Species Chemical Reaction Mechanism. Volume 2.
Author Carter, W. P. L. ; Lurmann, F. W. ; Atkinson, R. ; Lloyd, A. C. ;
CORP Author California Univ., Riverside. Statewide Air Pollution Research Center. ;Environmental Research and Technology, Inc., Newbury Park, CA.;Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab.
Year Published 1986
Report Number EPA-68-02-4104; EPA/600/3-86/031B;
Stock Number PB86-212412
Additional Subjects Ozone ; Atmospheric models ; Photochemical reactions ; Chemical reactions ; Atmospheric composition ; Air pollution ; Organic compounds ; Alkanes ; Alkene compounds ; Aromatic hydrocarbons ; Atmospheric chemistry ; Chemical reaction kinetics ; Smog chambers
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NTIS  PB86-212412 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 345p
Abstract A photochemical reaction mechanism has been updated and extensively evaluated. The testing and refinement of the surrogate species mechanism was performed in order to create an improved chemical mechanism for the atmospheric simulation models that are used to develop ozone control strategies. The updated mechanism was tested against 400 smog chamber experiments carried out in four different chambers. Tests were performed to assess the accuracy of the chamber characterization procedures, of reactions for single organic compounds, and of the overall mechanism for complex organic mixtures, including mixtures obtained from automobile exhaust. The results indicate that the mechanism's predictions are generally consistent with the experimental data. Volume II contains the results of the model simulations of the environmental chamber experiments and a summary and conclusion section that includes a discussion of work to be carried out in the future to adapt this mechanism for use in atmospheric modeling.
Supplementary Notes See also PB86-212404. Prepared in cooperation with Environmental Research and Technology, Inc., Newbury Park, CA. Sponsored by Environmental Protection Agency, Research Triangle Park, NC. Atmospheric Sciences Research Lab.
NTIS Title Notes Interim rept. for Oct 84-Feb 86.
PUB Date Free Form Jun 86
Category Codes 4A; 14B; 7C; 68A; 55E; 99D
NTIS Prices PC A15/MF A01
Primary Description 600/09
Document Type NT
Cataloging Source NTIS/MT
Control Number 624111487
Origin NTIS
Type CAT