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RECORD NUMBER: 224 OF 600

Main Title Effects of Ring Strain on Gas-Phase Rate Constants. 2. OH Radical Reactions with Cycloalkenes.
Author Atkinson, R. ; Aschmann, S. M. ; Carter, W. P. L. ;
CORP Author California Univ., Riverside. Statewide Air Pollution Research Center.;Environmental Sciences Research Lab., Research Triangle Park, NC.
Year Published 1983
Report Number EPA/600/J-83/314;
Stock Number PB86-101409
Additional Subjects Reaction kinetics ; Cycloalkenes ; Air pollution ; Reprints ; Hydroxyl radicals ; Atmospheric chemistry
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NTIS  PB86-101409 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 18p
Abstract Relative rate constants for the gas phase reactions of OH radicals with a series of cycloalkenes have been determined at 298 + or - 2 K, using methyl nitrite photolysis in air as a source of OH radicals. The data show that the rate constants for the nonconjugated cycloalkenes studied depend on the number of double bonds and the degree of substitution per double bond, and indicate that there are no obvious effects of ring strain energy on these OH radical addition rate constants. A predictive technique for the estimation of OH radical rate constants for alkenes and cycloalkenes is presented and discussed.
Availability Notes Pub. in International Jnl. of Chemical Kinetics, v15 p1161-1177 Nov 83.
NTIS Title Notes Journal article.
Title Annotations Reprint: Effects of Ring Strain on Gas-Phase Rate Constants. 2. OH Radical Reactions with Cycloalkenes.
PUB Date Free Form c1983
Category Codes 7D; 4A; 68A; 99F; 55E
NTIS Prices Not available NTIS
Primary Description 600/09
Document Type NT
Cataloging Source NTIS/MT
Control Number 535324709
Origin NTIS
Type CAT