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Main Title Kinetic Studies of the Reduction of Aromatic Azo Compounds in Anaerobic Sediment/Water Systems.
Author Weber, E. J. ; Wolfe, N. L. ;
CORP Author Environmental Research Lab., Athens, GA.
Year Published 1987
Report Number EPA/600/J-87/339;
Stock Number PB88-202460
Additional Subjects Water pollution ; Azo compounds ; Aromatic compounds ; Toxicology ; Chemical reactivity ; Reduction(Chemistry) ; Reprints ; Chemical kinetics ; Azobenzene ; Environmental fate
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NTIS  PB88-202460 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 11p
Abstract The reductive transformation of azobenzene and selected derivatives was investigated in anaerobic sediment/water systems. The azo compounds exhibited pseudo-first-order disappearance kinetics through at least three half-lives. The reduction kinetics of these compounds was studied as a function of their reduction potential and sediment/water distribution coefficient. There was no apparent correlation between the observed disappearance rate constant and reduction potential. Chemical sterilization of the sediment/water sample with formaldehyde and treatment with m-cresol, a dehydrogenase inhibitor, or sodium azide, a metabolic inhibitor, had little effect on the observed reduction rate constants for azobenzene, indicating an abiotic reduction process. Heat sterilization indicated that the reducing agent was heat labile.
Supplementary Notes Pub. in Environmental Toxicology and Chemistry, v6 n12 p911-919 Dec 87.
NTIS Title Notes Journal article.
Title Annotations Reprint: Kinetic Studies of the Reduction of Aromatic Azo Compounds in Anaerobic Sediment/Water Systems.
PUB Date Free Form 1987
Category Codes 57Y; 68D; 99C
NTIS Prices PC A03/MF A01
Primary Description 600/01
Document Type NT
Cataloging Source NTIS/MT
Control Number 819623420
Origin NTIS
Type CAT