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Main Title Deactivation of H2S of Cr2O3 emission control catalyst for chlorinated VOC destruction /
Author Narayanan, Sundar. ; Greene, H. L. ; Nunez, C. M.
Other Authors
Author Title of a Work
Greene, Howard L.
Nunez, Carlos M.
CORP Author Akron Univ., OH. Dept. of Chemical Engineering.;Environmental Protection Agency, Research Triangle Park, NC. Air and Energy Engineering Research Lab.
Publisher U.S. Environmental Protection Agency, Office of Research and Development, Air and Energy Engineering Research Laboratory,
Year Published 1990
Report Number EPA/600/D-90/103; AEERL-P-646; EPA-R-815095
Stock Number PB90-262841
Additional Subjects Annual AWMA Conference, June 24-29 :--(83rd--1990 :--Pittsburgh, PA) ; Waste disposal ; Air pollution control ; Catalysts ; Laboratory equipment ; Hydrogen sulfide ; Performance evaluation ; Chlorohydrocarbons ; Chemical reactions ; Surface chemistry ; Catalysis ; Selectivity ; Deactivation ; Incineration ; Volatile organic compounds ; Poisoning
Library Call Number Additional Info Location Last
NTIS  PB90-262841 Some EPA libraries have a fiche copy filed under the call number shown. 07/26/2022
Collation 21 pages ; 28 cm
Abstract The paper discusses one aspect of catalyst stability (i.e., deactivation by poisoning) and the concomitant effects on catalyst activity and selectivity in the destruction of chlorinated hydrocarbons. The study was initiated because nothing is documented of the effect of H2S or the other sulfurous poisons on the performance of catalysts in the specific application of oxidative destruction of chlorinated volatile organic compounds (VOCs). A chromia (Cr2O3) catalyst, commercially popular for the destruction of chlorinated hydrocarbons, was chosen for the study of H2S poisoning effects, which concentrated on the activity, selectivity, and stability trends of the catalyst to H2S. Study results indicate that poisoning of the catalyst by H2S brings about mixed effects. While activities generally decreased, the selectivities to HCl and chloroform became more favorable and the selectivity to CO2 decreased.
Notes Caption title. "EPA/600/D-90/103." "Carlos M. Nunez, project officer." Microfiche.
Place Published Research Triangle Park, NC :
Supplementary Notes Presented at the Annual Meeting of the Air and Waste Management Association (83rd), Pittsburgh, PA., June 24-29, 1990. Sponsored by Environmental Protection Agency, Research Triangle Park, NC. Air and Energy Engineering Research Lab.
Corporate Au Added Ent United States. Environmental Protection Agency. Office of Research and Development. ; Air and Energy Energineering Research Laboratory. ; University of Akron. Department of Chemical Engineering.
PUB Date Free Form 1990.
NTIS Prices PC A03/MF A01
BIB Level m
Cataloging Source OCLC/T
OCLC Time Stamp 20001213144442
Language eng
Origin NTIS
OCLC Rec Leader 01392cam 2200301Ka 45170