| Main Title |
Oxidation of Chlorinated Ethanes. |
| Author |
Spence, John W. ;
Hanst., Philip L. ;
|
| CORP Author |
Environmental Sciences Research Lab., Research Triangle Park, N.C. |
| Year Published |
1978 |
| Report Number |
EPA/600/J-78/008; |
| Stock Number |
PB-281 017 |
| Additional Subjects |
Oxidation ;
Chloroethanes ;
Chlorine aliphatic compounds ;
Infrared spectroscopy ;
Stability ;
Phosgene ;
Hydrogen chloride ;
Acetyl chloride ;
Chemical reactions ;
Chemical reaction mechanisms ;
Fourier transform spectroscopy ;
Atmospheric chemistry ;
Long path infrared spectroscopy ;
Formyl chloride ;
Chloroform/methyl ;
Reprints
|
| Holdings |
| Library |
Call Number |
Additional Info |
Location |
Last
Modified |
Checkout
Status |
| NTIS |
PB-281 017 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
| Collation |
5p |
| Abstract |
The oxidation products of seven chlorinated ethanes were identified using Fourier Transform Spectroscopy and long path infrared techniques. Photo-oxidation of each chlorinated ethane was initiated by chlorine atoms in one atmosphere of dry air. The chlorinated reaction products included phosgene, formyl chloride, hydrogen chloride, acetyl chloride, and chlorinated acetyl chlorides. Five rules concerning the initiation reaction and the stability of the intermediate products were set forth and were used to explain the photooxidation steps of each chlorinated ethane. Methyl chloroform was the least reactive of the chlorinated ethanes. |
| Availability Notes |
Pub. in Jnl. of the Air Pollution Control Association, n28 n3 p250-253, Mar 78. |
| NTIS Title Notes |
Journal article. |
| Title Annotations |
Reprint: Oxidation of Chlorinated Ethanes. |
| PUB Date Free Form |
c1978 |
| Category Codes |
7E; 4A; 68A; 99E; 55E |
| NTIS Prices |
Not available NTIS |
| Primary Description |
600/09 |
| Document Type |
NT |
| Cataloging Source |
NTIS/MT |
| Control Number |
323741518 |
| Origin |
NTIS |
| Type |
CAT |
