| Main Title |
Rate Constants for the Gas-Phase Reactions of OH Radicals with a Series of Bi- and Tricycloalkanes at 299 + or - 2 K: Effects of Ring Strain. |
| Author |
Atkinson, R. ;
Aschmann, S. M. ;
Carter, W. P. L. ;
|
| CORP Author |
California Univ., Riverside. Statewide Air Pollution Research Center.;Environmental Sciences Research Lab., Research Triangle Park, NC. |
| Year Published |
1983 |
| Report Number |
EPA/600/J-83/313; |
| Stock Number |
PB86-101730 |
| Additional Subjects |
Reaction kinetics ;
Cycloalkane hydrocarbons ;
Rings ;
Air pollution ;
Molecular structure ;
Reprints ;
Hydroxyl radicals ;
Atmospheric chemistry
|
| Holdings |
| Library |
Call Number |
Additional Info |
Location |
Last
Modified |
Checkout
Status |
| NTIS |
PB86-101730 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
| Collation |
16p |
| Abstract |
Relative rate constants for the gas phase reactions of OH radicals with a series of bi- and tri-cyclic alkanes have been determined at 299 + or - 2K, using methyl nitrite photolysis in air as a source of OH radicals. The data show that overall ring strain energies of < or - 4-5 kcal mole-1 have no significant effect on the rate constants, but that larger ring strain results in the rate constants being decreased, relative to those expected for the strain-free molecules, by ratios which increase approximately exponentially with the overall ring strain. |
| Availability Notes |
Pub. in International Jnl. of Chemical Kinetics, v15 p37-50 Jan 83. |
| NTIS Title Notes |
Journal article. |
| Title Annotations |
Reprint: Rate Constants for the Gas-Phase Reactions of OH Radicals with a Series of Bi- and Tricycloalkanes at 299 + or - 2 K: Effects of Ring Strain. |
| PUB Date Free Form |
c1983 |
| Category Codes |
7D; 4A; 68A; 99F; 55E |
| NTIS Prices |
Not available NTIS |
| Primary Description |
600/09 |
| Document Type |
NT |
| Cataloging Source |
NTIS/MT |
| Control Number |
535324807 |
| Origin |
NTIS |
| Type |
CAT |
