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RECORD NUMBER: 4 OF 5

OLS Field Name OLS Field Data
Main Title Analysis of Technical Chlordane by Gas Chromatography Mass Spectrometry.
Author Sovocool, G. Wayne ; Lewis, Robert G. ; Harless, Robert L. ; Wilson, Nancy K. ; Zehr., Robert D. ;
CORP Author Health Effects Research Lab., Research Triangle Park, N.C. Environmental Toxicology Div.
Year Published 1977
Report Number EPA/600/J-77/087;
Stock Number PB-278 593
Additional Subjects Chlordan ; Pesticides ; Chemical analysis ; Gas chromatography ; Mass spectroscopy ; Molecular structure ; Chlorine organic compounds ; Cyclopentadiene compounds ; Reprints ; Cyclopentadiene/hexachloro ; Cyclopentadiene/tetrachloro ; Cyclopentadiene/pentachloro
Holdings
Library Call Number Additional Info Location Last
Modified
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Status
NTIS  PB-278 593 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 06/23/1988
Collation 9p
Abstract
The composition of technical chlordane has been investigated by combined gas chromatography/mass spectrometry, employing a column commonly used for pesticide residue analysis. Partial or complete structure identification have been assigned to some 45 individual constituents. Many of these compounds are simple Diels-Alder adducts of cyclopentadiene and hexachlorocyclopentadiene, with further chlorine addition or substitution. Additionally, a series of adducts derived from tetra- and pentachlorocyclopentadiene, followed by further chlorination, has been identified. Several components appear to have incorporated trichloromethyl moieties from the solvent during manufacture. Other compounds with abnormal or rearranged ring fusions have also been recognized and their unusual mass spectra have been studied.