Main Title |
Efficency of gas-wall reactions in a cylindrical flow reactor / |
Author |
Judeikis, Henry S. ;
Siegel., Seymour
|
Other Authors |
|
CORP Author |
Aerospace Corp., El Segundo, Calif.;Environmental Sciences Research Lab., Research Triangle Park, N.C. Atmospheric Chemistry and Physics Div. |
Publisher |
Environmental Sciences Research Laboratory, Office of Research and Development, U.S. Environmental Protection Agency, |
Year Published |
1977 |
Report Number |
EPA-600/3-77-043; ATR-73(7256)-2; EPA-R-802687 |
Stock Number |
PB-269 005 |
OCLC Number |
52414057 |
Subjects |
Chemical reactions ;
Air--Pollution
|
Additional Subjects |
Surface chemistry ;
Gases ;
Chemical reactions ;
Diffusion ;
Numerical analysis ;
Pressure ;
Chemical reactors ;
Gas wall interactions
|
Internet Access |
|
Holdings |
Library |
Call Number |
Additional Info |
Location |
Last Modified |
Checkout Status |
EJBD |
EPA 600-3-77-043 |
|
Headquarters Library/Washington,DC |
03/07/2014 |
EKBD |
EPA-600/3-77-043 |
|
Research Triangle Park Library/RTP, NC |
07/11/2003 |
ELBD ARCHIVE |
EPA 600-3-77-043 |
Received from HQ |
AWBERC Library/Cincinnati,OH |
10/04/2023 |
ESAD |
EPA 600-3-77-043 |
|
Region 10 Library/Seattle,WA |
03/23/2010 |
NTIS |
PB-269 005 |
Some EPA libraries have a fiche copy filed under the call number shown. |
|
07/26/2022 |
|
Collation |
19 p. : ill. ; 28 cm. |
Abstract |
Expressions are given for the concentration of a dilute reactive gas mixed with an inert carrier gas as a function of the radial and longitudinal distances in a cylindrical reactor and the reaction efficiency. The reaction efficiency is defined as the fraction of gas-wall collisions that leads to the disappearance of the reactive gas from the gas phase. The solutions presented here are applicable for all values of reaction efficiencies and extend earlier work by other investigators that was applicable only for values of 1 or near zero. In addition to the solution of Fick's second law of diffusion as applied here (with an additional term for flow in the cylinder), a one-dimensional random walk analysis is also applied to this problem. The combination of diffusion equation solutions and the random walk analysis leads to the conclusion that, for a given set of experimental conditions, the reaction efficiency can be uniquely determined only if it lies within a certain range of values. Small values of the reaction efficiency will produce insufficient reaction and large values will yield diffusion-limited results. |
Notes |
"EPA-600/3-77-043." "May 1977." Includes bibliographical references (p. 18). |