Record Display for the EPA National Library Catalog

RECORD NUMBER: 24 OF 391

OLS Field Name OLS Field Data
Main Title Biomass Reactivity in Gasification by the Hynol Process.
Author Dong, Y. ; Borgwardt, R. H. ;
CORP Author Acurex Environmental Corp., Research Triangle Park, NC.;Environmental Protection Agency, Research Triangle Park, NC. Air Pollution Prevention and Control Div.
Publisher 1995
Year Published 1995
Report Number EPA-68-D4-0005; EPA/600/A-97/010;
Stock Number PB97-192397
Additional Subjects Biomass conversion ; Chemical reactivity ; Poplars ; Gasification ; Carbinols ; Chemical reactors ; Chemical reaction kinetics ; Pyrolysis ; Volatile matter ; Particle size ; Temperature dependence ; Devolatilization ; Methanol fuels ; Mathematical models ; Greenhouse gases ; Air pollution abatement ; Hynol process
Internet Access
Description Access URL
https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=P100VBA2.PDF
Holdings
Library Call Number Additional Info Location Last
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Status
NTIS  PB97-192397 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 12/22/1997
Collation 7p
Abstract
The paper discusses the use of a thermobalance reactor to evaluate the reactivity of popular wood in gasification under the operating conditions specific for the Hynol process (30 atm and 800 C). The gasification involved a rapid devolization and pyrolysis reaction of the volatile matter in biomass and slow reaction of residual carbon with the process gas. Gasification rate and biomass conversion were strongly affected by reaction temperature and particle size. The conversion was proportional to the partial pressures of hydrogen and steam in the feed gas. A kinetic model was developed to correlate the experimental data and quantitatively express gasification rates and biomass conversion as functions of reaction time. The activation energies for the rapid and slow reactions were estimated to be 3.8 and 34 kcal/mol, respectively.