Record Display for the EPA National Library Catalog
RECORD NUMBER: 658 OF 1380Main Title | Formation of Aerosols in a Photochemical Fast Flow Reactor. | |||||||||||
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Author | Lipeles, M. ; Landis, D. A. ; Hidy., G. M. ; | |||||||||||
CORP Author | Rockwell International Corp., Thousand Oaks, Calif. Science Center.;Environmental Protection Agency, Research Triangle Park, N.C.;Coordinating Research Council, Inc., New York. | |||||||||||
Year Published | 1975 | |||||||||||
Report Number | SC551.17FR; EPA-68-02-0771; CRC-APRAC-CAPA-8-71-4; | |||||||||||
Stock Number | PB-248 590 | |||||||||||
Additional Subjects | Aerosols ; Air pollution ; Photochemical reactions ; Ozone ; Laboratory equipment ; Actinometry ; Flow rate ; Design criteria ; Air filters ; Condensation nuclei ; Extractions ; Infrared spectra ; Chemical analysis ; Concentration(Composition) ; Hydrocarbons ; Hexenes ; Toluene ; Xylenes ; Sulfur dioxide ; Water ; Ammonia ; Terpenes ; Alkine hydrocarbons ; O-heterocyclic compounds ; Air pollution sampling ; Fast flow reactors ; Prototype reactors ; Chemical reaction mechanisms ; Hexadiene ; Dodecenes ; Pinenes | |||||||||||
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Collation | 75p | |||||||||||
Abstract | This report details work performed on the study of aerosol formation in a photochemical fast flow reactor which may be operated in a 'wall free' mode. Aerosols have been produced in this reactor in irradiated dry air containing typically 0.8 ppm NO2 and 10 ppm of one hydrocarbon. The hydrocarbons studied were alpha-pinene, 1-hexene, cyclohexene, 1-dodecene, toluene, m-xylene, 1,3-hexadiene, and 1,5 hexadiene. The effect of the addition of various mixtures of SO2, H2O and NH3 to the reactions was studied. Ozone and condensation nuclei concentration were measured in the reactor as a function of reactant concentration. Total mass production was measured by filter collection, and infrared spectra of some of the samples have been obtained. |