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RECORD NUMBER: 1 OF 5

OLS Field Name OLS Field Data
Main Title Effect of fuel sulfur on NOx emissions from premixed flames /
Author Wendt, J. O. L. ; Wendt, Jost Otto Lutz ; Ekmann., J. M.
Other Authors
Author Title of a Work
Ekmann, James Michael.
CORP Author Arizona Univ., Tucson. Dept. of Chemical Engineering.;Industrial Environmental Research Lab., Research Triangle Park, N.C.
Publisher U.S. Environmental Protection Agency, Industrial Environmental Research Laboratory,
Year Published 1975
Report Number EPA 600/2-75/075; EPA-R-802204; EPA-ROAP-21ADG-021
Stock Number PB-248 099
OCLC Number 42740306
Subjects Combustion--Research. ; Nitrogen oxides. ; Sulfur compounds. ; Combustion--Research.surement ; Sulphur compounds
Additional Subjects Nitrogen oxides ; Air pollution ; Atmospheric chemistry ; Sulfur dioxide ; Hydrogen sulfide ; Laboratory equipment ; Mathematical models ; Thermochemistry ; Combustion products ; Desulfurization ; Simulation ; Computer programming ; Reaction kinetics ;
Internet Access
Description Access URL
https://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=91014IS0.PDF
Holdings
Library Call Number Additional Info Location Last
Modified
Checkout
Status
EJBD ARCHIVE EPA 600-2-75-075 Headquarters Library/Washington,DC 02/11/2014
EKAM  EPA 600/2-75/075 Region 4 Library/Atlanta,GA 11/05/1999
EKBD  EPA-600/2-75-075 Research Triangle Park Library/RTP, NC 06/13/2003
ESAD  EPA 600-2-75-075 Region 10 Library/Seattle,WA 03/23/2010
NTIS  PB-248 099 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. 06/23/1988
Collation v, 86 p. : ill. ; 28 cm.
Abstract
The report gives results of an investigation of the effect of fuel sulfur compounds on nitrogen oxides (NOx) emissions from premixed gaseous flames. Laboratory measurements, using a methane/air flat flame doped with SO2 or H2S, showed that fuel sulfur inhibits the formation of NOx arising from thermal fixation. This inhibition was significant at all air/fuel ratios and especially at high air preheats. The effect of fuel sulfur on formation of NOx arising from fuel nitrogen oxidation is less clear because of complex reactions between sulfur- and nitrogen-containing species in both the flame and the sampling probe. A mathematical simulation of a flat flame was developed that showed that the observed effect of fuel sulfur on 'thermal NO' could be explained by a kinetic mechanism involving the catalysis of atom recombination reactions by SO2. The experimental and theoretical results may be especially significant from a practical point of view, since they appear to indicate that fuel desulfurization may lead to increased NOx emissions.
Notes
"EPA-600/2-75-075" -- Cover. EPA grant no. R-802204; EPA project officer: W.S. Lanier. Includes bibliographical references (p. 59-61). "EPA 600/2-75/075".