Record Display for the EPA National Library Catalog

RECORD NUMBER: 5 OF 16

OLS Field Name OLS Field Data
Main Title Detection of Hydroxylated Nitro Aromatic and Hydroxylated Nitro Polycyclic Aromatic Compounds in an Ambient Air Particulate Extract Using Bioassay-Directed Fractionation.
Author Nishioka, M. G. ; Howard, C. C. ; Contos, D. A. ; Ball, L. M. ; Lewtas, J. ;
CORP Author Battelle Columbus Labs., OH. ;North Carolina Univ. at Chapel Hill. Dept. of Environmental Sciences and Engineering.;Health Effects Research Lab., Research Triangle Park, NC.
Publisher c1988
Year Published 1988
Report Number EPA-68-02-3745; EPA/600/J-88/341;
Stock Number PB89-237432
Additional Subjects Aromatic polycylic hydrocarbons ; Air pollution ; Distillation ; Detection ; Bioassay ; Gas chromatography ; Mass spectroscopy ; Reprints ;
Holdings
Library Call Number Additional Info Location Last
Modified
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Status
NTIS  PB89-237432 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. NTIS 12/18/1989
Collation 11p
Abstract
The report identifies hydroxylated nitro-polynuclear aromatic hydrocarbons (OH-NO2PAHs) in an ambient air particulate extract by electron impact (EI) and negative chemical ionization (NCI) high resolution gas chromatography/mass spectrometry (HRGC/MS) analyses. Bioassay-directed fractionation through three sequential separations led to detection of these OH-NO2-PAHs in a highly mutagenic and substantially simplified subfraction of the extract. The compound class identification was based on comparison of both EI and NCI mass spectra of reference OH-NO2-pyrenes. The HRGC/MC retention values for seven OH-NO2-fluoranthene isomer. Quantification of this compound class by NCI HRGC/MC with on-column injection is demonstrated with sensitivity to 0.5 ng/micro L.