Record Display for the EPA National Library Catalog

RECORD NUMBER: 16 OF 25

OLS Field Name OLS Field Data
Main Title Moving Belt Interface with Spray Deposition for Liquid Chromatography/Mass Spectrometry.
Author Hayes, M. J. ; Lankmayer, E. P. ; Vouros, P. ; Karger, B. L. ; McGuire, J. M. ;
CORP Author Northeastern Univ., Boston, MA.;Environmental Research Lab., Athens, GA.
Year Published 1983
Report Number EPA-600/J-83-108;
Stock Number PB84-124957
Additional Subjects Chemical analysis ; Mass spectroscopy ; Spraying ; Belts ; Performance evaluation ; Chromatographic analysis ; Aromatic polycyclic hydrocarbons ; Environmental surveys ; Water pollution ; Reprints ; Liquid chromatography ; High performance liquid chromatography ; Water pollution detection
Holdings
Library Call Number Additional Info Location Last
Modified
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Status
NTIS  PB84-124957 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. 06/23/1988
Collation 11p
Abstract
A systematic study of the chromatographic performance of a moving belt interface for LC/MS was conducted. For this work a specially designed nebulizer was constructed for deposition of the effluent from the LC column onto the moving belt. The role of various parameters of the nebulizer (e.g., gas flow rate and temperature) on chromatographic performance, as measured by the second moment of the generated chromatographic profiles, was examined. The influence of belt speed on peak variance was also examined. On the basis of these studies, the LC separation with normal bore (4.6 mm i.d.) columns was obtained under high-performance conditions along with mass spectral analyses of complex mixtures of substances. Successful operation with mobile phases of high water content was also achieved. In addition, detection limits as low as 40 pg were measured in the EI mode with polynuclear aromatic hydrocarbons, with linear dynamic ranges of at least 4 orders of magnitude. These studies demonstrate the utility of the moving belt interface for on-line high-performance LC/MS. (Copyright (c) 1983 by the American Chemical Society.)