Record Display for the EPA National Library Catalog

RECORD NUMBER: 7 OF 11

OLS Field Name OLS Field Data
Main Title Oxidation of Chlorinated Ethanes.
Author Spence, John W. ; Hanst., Philip L. ;
CORP Author Environmental Sciences Research Lab., Research Triangle Park, N.C.
Year Published 1978
Report Number EPA/600/J-78/008;
Stock Number PB-281 017
Additional Subjects Oxidation ; Chloroethanes ; Chlorine aliphatic compounds ; Infrared spectroscopy ; Stability ; Phosgene ; Hydrogen chloride ; Acetyl chloride ; Chemical reactions ; Chemical reaction mechanisms ; Fourier transform spectroscopy ; Atmospheric chemistry ; Long path infrared spectroscopy ; Formyl chloride ; Chloroform/methyl ; Reprints
Holdings
Library Call Number Additional Info Location Last
Modified
Checkout
Status
NTIS  PB-281 017 Most EPA libraries have a fiche copy filed under the call number shown. Check with individual libraries about paper copy. 06/23/1988
Collation 5p
Abstract
The oxidation products of seven chlorinated ethanes were identified using Fourier Transform Spectroscopy and long path infrared techniques. Photo-oxidation of each chlorinated ethane was initiated by chlorine atoms in one atmosphere of dry air. The chlorinated reaction products included phosgene, formyl chloride, hydrogen chloride, acetyl chloride, and chlorinated acetyl chlorides. Five rules concerning the initiation reaction and the stability of the intermediate products were set forth and were used to explain the photooxidation steps of each chlorinated ethane. Methyl chloroform was the least reactive of the chlorinated ethanes.