Record Display for the EPA National Library Catalog
RECORD NUMBER: 10 OF 14
|OLS Field Name||OLS Field Data|
|Main Title||Photochemical oxidation of kraft air pollutants /|
|Author||Bentley., Michael D.|
|CORP Author||Maine Univ., Orono.;National Environmental Research Center, Research Triangle Park, N.C. Chemical and Physics Lab.|
|Publisher||Chemistry and Physics Laboratory, National Environmental Research Center,|
|Report Number||EPA-650/3-75-005; EPA-600/3-75-005; EP-800209; EPA-ROAP-26AAD-14|
|Subjects||Photochemical oxidants. ; Atmospheric chemistry. ; Oxidation.|
|Additional Subjects||Photochemical reactions ; Organic sulfides ; Air pollution ; Pulp mills ; Sulfate pulping ; Oxidation reactions ; Methane thiols ; Disulfide/dimethyl ; Thiols|
|Collation||v, 11 leaves : illustrations ; 28 cm.|
The photolysis of methyl mercaptan, dimethyldisulfide, and methylmethanethiolsulfonate were studied. The photolysis of methyl mercaptan in air was shown to yield dimethyl disulfide, methanesulfonic acid, ethyl mercaptan, methanol, formic acid, methane, sulfur trioxide, and sulfur dioxide in addition to other presently unidentified compounds. The photolysis of dimethyldisulfide in air was shown to yield methanesulfonic acid, methylmethanethiolsulfonate, methanesulfinic acid, methyl formate, sulfur, sulfur dioxide, sulfur trioxide, and other presently unidentified compounds. The photolysis of methylmethanethiolsulfonate in tetrahydrofuran resulted in formation of methane, methyl mercaptan, dimethyl sulfide, dimethyldisulfide, methanesulfinic acid, methanesulfonic acid, and sulfur dioxide. N-isopropyl-S-benzylsulfenamide was found to undergo an unusual thermal elimination to form N-isopropylbenzaqlimine. Lithium amides were found to form sulfenamides upon reaction with disulfide.
"EPA Project Officer: Dr. Marcia Dodge." "Prepared for U.S. Environmental Protection Agency, Office of Research and Development." "EPA-650/3-75-005 " "May 1975." "Grant No. 800209; Project No. 26AAD-14; Program Element No. 1A1008." PB 243 599--NTIS. Includes bibliographical references (page 11).